Complete this prelab assignment (questions 1-3) on these sheets in the spaces provided. Combine this along with a scanned copy of your Lab Notebook and upload to CANVAS before the beginning of your Lab Section. *. In Part A of this experiment, you prepare 5 solutions of FeSCN2* [one of them is just a blank solution] according to the reaction below. Fe3+ (aq) + SCN- (aq) → FeSCN²+ (aq) We assume that the starting SCN determines the concentration of formed (because Fe3+ is in excess and SCN- is limiting). Calculate the concentration of FeSCN2* that forms for each of the solution (Beakers 1-4) and fill out the table below. Show your calculations beneath the table.

Chemistry: The Molecular Science
5th Edition
ISBN:9781285199047
Author:John W. Moore, Conrad L. Stanitski
Publisher:John W. Moore, Conrad L. Stanitski
Chapter3: Chemical Reactions
Section: Chapter Questions
Problem 125QRT: A student set up an experiment for six different trials of the reaction between 1.00-M aqueous...
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Correct numbers 1 and 3. Show all work/calculations:

Complete this prelab assignment (questions 1-3) on these sheets in the spaces provided. Combine this
along with a scanned copy of your Lab Notebook and upload to CANVAS before the beginning of your
Lab Section.
*. In Part A of this experiment, you prepare 5 solutions of FESCN2* [one of them is just a blank
solution] according to the reaction below.
Fe3+ (aq) + SCN¯ (aq) → FeSCN²+ (aq)
We assume that the starting SCN determines the concentration of formed (because Fe3+ is in
excess and SCN" is limiting). Calculate the concentration of FESCN2* that forms for each of the
solution (Beakers 1- 4) and fill out the table below. Show your calculations beneath the table.
Beaker
0.200 M
0.0020 M
Concentration of
Number
Fe(NO3)3 (mL]
KSCN (mL]
H20 [mL]
FESCN2* (M)
1
5.0
5.0
40.0
0.0002
2
5.0
4.0
41.0
0.00016
5.0
3.0
42.0
0.00012
4
5.0
2.0
43.0
0.00008
5 (blank)
5.0
0.0
45.0
181
Show your work for question 1 here:
Total volume of all beakers = 50 mL
MSCN x VSCN
(FESCN2*] = (SCN'] =
values ok but,
you Should
NOT use
Total Volume
Beaker 1:
0.002 x 5
(FESCN2"] =
50
= 0.0002 M
%3D
Beaker 2:
0.002 x 4
(FESCN²*] =
50
= 0.00016 M
MiVi=M2V2
Beaker 3:
Show mol ratio
0.002 x 3
(FESCN2*] =
50
= 0.00012 M
Beaker 4:
0.002 x 4
(FESCN2"] =
50
= 0.00008 M
2. In Part A, you measure the absorbance of four FeSCN2* solutions and prepare a Beer's Law plot
(Absorbance vs. wavelength] similar to the one below.
Beer's Law Plot for FeSCN2+
0.6
y = 2417.5x + 0.0483
R? = 0.999
0.5
E
0.4
0.3
0.2
0.1
0.00005
0.0001
0.00015
0.0002
0.00025
Concentration (M)
You will use this plot as a standard curve in Part B to determine the concentration of an
unknown. If an unknown FeSCN2* solution gives an absorbance reading of 0.334, use the
equation of the best fit line shown above to determine its concentration. Show all work below.
Absorbance
Transcribed Image Text:Complete this prelab assignment (questions 1-3) on these sheets in the spaces provided. Combine this along with a scanned copy of your Lab Notebook and upload to CANVAS before the beginning of your Lab Section. *. In Part A of this experiment, you prepare 5 solutions of FESCN2* [one of them is just a blank solution] according to the reaction below. Fe3+ (aq) + SCN¯ (aq) → FeSCN²+ (aq) We assume that the starting SCN determines the concentration of formed (because Fe3+ is in excess and SCN" is limiting). Calculate the concentration of FESCN2* that forms for each of the solution (Beakers 1- 4) and fill out the table below. Show your calculations beneath the table. Beaker 0.200 M 0.0020 M Concentration of Number Fe(NO3)3 (mL] KSCN (mL] H20 [mL] FESCN2* (M) 1 5.0 5.0 40.0 0.0002 2 5.0 4.0 41.0 0.00016 5.0 3.0 42.0 0.00012 4 5.0 2.0 43.0 0.00008 5 (blank) 5.0 0.0 45.0 181 Show your work for question 1 here: Total volume of all beakers = 50 mL MSCN x VSCN (FESCN2*] = (SCN'] = values ok but, you Should NOT use Total Volume Beaker 1: 0.002 x 5 (FESCN2"] = 50 = 0.0002 M %3D Beaker 2: 0.002 x 4 (FESCN²*] = 50 = 0.00016 M MiVi=M2V2 Beaker 3: Show mol ratio 0.002 x 3 (FESCN2*] = 50 = 0.00012 M Beaker 4: 0.002 x 4 (FESCN2"] = 50 = 0.00008 M 2. In Part A, you measure the absorbance of four FeSCN2* solutions and prepare a Beer's Law plot (Absorbance vs. wavelength] similar to the one below. Beer's Law Plot for FeSCN2+ 0.6 y = 2417.5x + 0.0483 R? = 0.999 0.5 E 0.4 0.3 0.2 0.1 0.00005 0.0001 0.00015 0.0002 0.00025 Concentration (M) You will use this plot as a standard curve in Part B to determine the concentration of an unknown. If an unknown FeSCN2* solution gives an absorbance reading of 0.334, use the equation of the best fit line shown above to determine its concentration. Show all work below. Absorbance
You will use this plot as a standard curve in Part B to determine the concentration of an
unknown. If an unknown FeSCN2* solution gives an absorbance reading of 0.334, use the
equation of the best fit line shown above to determine its concentration. Show all work below.
y = absorbance = 0.334
y = 2417.5x + 0.0483
y - 0.0483
X =
0.334 - 0.0483
2417.5
2417.5
x = 1.182 x 10-4 M
Unknown [FESCN²*] = 1.182 x 10-4 M
%3D
182
3. In Part C, you prepare four solutions (starting concentrations are given blow) in test tubes and
you will measure the Absorbance after the solutions have reached equilibrium. Shown below is
an example of just ONE solution, with absorbance data shown as well. Using this data and the
standard curve from question 2 on the previous page, calculate Kf.
SHOW ALL WORK BELOW!
Starting Concentrations
Test Tube
0.00200 M Fe(NO3)3 [mL] 0.0020 M KSCN [mL]
H20 [mL]
1
3.0
2.0
5.0
Absorbance Data
(FESCN²*] at
Test Tube
Absorbance at Amax
equilibrium
Kf
1
0.118
2.88 x 10-4 M
121
Given absorbance: y = 0.118
y – 0.0483
X =
0.118 – 0.0483
2417.5
2417.5
x = 2.883 x 10'5 M
(FESCN2*] = 2.88 x 10$ M
(Fe**) =;
MFex VFe
0.002 x 3
= 0.006 M
Total Volume
MSCN X V SCN
10
0.002 x 2
[SCN'] =
= 0.0004 M
%3D
Total Volume
10
ICE Table:
Fe3+
SCN-
FESCN2+
0.006
0.0004
C
-X
-X
+X
E
0.006 – x
0.004 - x
[FESCN2*]
Kf =
[Fe3+][SCN¯]
0.118 = 2417.5+ 0.0483
2417.5x = 0.334 – 0.0483 = 0.0697
(0.006 – x)(0.004 – x)
0.0697
X =
2417.5
= 2.88 x 10-5 M
At equilibrium,
(FESCN2*] = 2.88 x 105 M
(Fe3*] = 0.0060 – x = 0.0060 – 2.88 x 105 = 0.0059712
(SCN'] = 0.0040 – x = 0.0040 – 2.88 x 10$ = 0.0039712 not Sure what
went wrong.-.
2.88 x 10-5
Kf =
(0.0059712 x 0.0039712)
Kf = 121
Transcribed Image Text:You will use this plot as a standard curve in Part B to determine the concentration of an unknown. If an unknown FeSCN2* solution gives an absorbance reading of 0.334, use the equation of the best fit line shown above to determine its concentration. Show all work below. y = absorbance = 0.334 y = 2417.5x + 0.0483 y - 0.0483 X = 0.334 - 0.0483 2417.5 2417.5 x = 1.182 x 10-4 M Unknown [FESCN²*] = 1.182 x 10-4 M %3D 182 3. In Part C, you prepare four solutions (starting concentrations are given blow) in test tubes and you will measure the Absorbance after the solutions have reached equilibrium. Shown below is an example of just ONE solution, with absorbance data shown as well. Using this data and the standard curve from question 2 on the previous page, calculate Kf. SHOW ALL WORK BELOW! Starting Concentrations Test Tube 0.00200 M Fe(NO3)3 [mL] 0.0020 M KSCN [mL] H20 [mL] 1 3.0 2.0 5.0 Absorbance Data (FESCN²*] at Test Tube Absorbance at Amax equilibrium Kf 1 0.118 2.88 x 10-4 M 121 Given absorbance: y = 0.118 y – 0.0483 X = 0.118 – 0.0483 2417.5 2417.5 x = 2.883 x 10'5 M (FESCN2*] = 2.88 x 10$ M (Fe**) =; MFex VFe 0.002 x 3 = 0.006 M Total Volume MSCN X V SCN 10 0.002 x 2 [SCN'] = = 0.0004 M %3D Total Volume 10 ICE Table: Fe3+ SCN- FESCN2+ 0.006 0.0004 C -X -X +X E 0.006 – x 0.004 - x [FESCN2*] Kf = [Fe3+][SCN¯] 0.118 = 2417.5+ 0.0483 2417.5x = 0.334 – 0.0483 = 0.0697 (0.006 – x)(0.004 – x) 0.0697 X = 2417.5 = 2.88 x 10-5 M At equilibrium, (FESCN2*] = 2.88 x 105 M (Fe3*] = 0.0060 – x = 0.0060 – 2.88 x 105 = 0.0059712 (SCN'] = 0.0040 – x = 0.0040 – 2.88 x 10$ = 0.0039712 not Sure what went wrong.-. 2.88 x 10-5 Kf = (0.0059712 x 0.0039712) Kf = 121
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