Consider an aqueous 4.00 m solution of NazP04, a compound with useful detergent properties (kp = 0.51 °C m1). (a) Calculate the boiling point of the solution on the assumption that it does not ionize at all in solution. 100.51 (b) Do the same calculation, assuming that the van't Hoff factor for NazPO4 reflectes 100% dissociation into ions. 103.57 °C (c) The 4.00 m solution boils at 100.290 °C at 1 atm. Calculate the van't Hoff factor for the solute in this solution. 0.53

Chemistry: Principles and Practice
3rd Edition
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Author:Daniel L. Reger, Scott R. Goode, David W. Ball, Edward Mercer
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Chapter12: Solutions
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Problem 12.82QE: The freezing point of a 0.031-m solution of copper(II) sulfate in water is 0.075 C. (a) Calculate...
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Consider an aqueous 4.00 m solution of NazP04, a compound with useful detergent properties (kp = 0.51 °C m1).
(a) Calculate the boiling point of the solution on the assumption that it does not ionize at all in solution.
100.51
(b) Do the same calculation, assuming that the van't Hoff factor for Na3PO4 reflectes 100% dissociation into ions.
103.57
°C
(c) The 4.00 m solution boils at 100.290 °C at 1 atm. Calculate the van't Hoff factor for the solute in this solution.
0.53
Transcribed Image Text:Consider an aqueous 4.00 m solution of NazP04, a compound with useful detergent properties (kp = 0.51 °C m1). (a) Calculate the boiling point of the solution on the assumption that it does not ionize at all in solution. 100.51 (b) Do the same calculation, assuming that the van't Hoff factor for Na3PO4 reflectes 100% dissociation into ions. 103.57 °C (c) The 4.00 m solution boils at 100.290 °C at 1 atm. Calculate the van't Hoff factor for the solute in this solution. 0.53
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