
Chemistry: The Molecular Science
5th Edition
ISBN: 9781285199047
Author: John W. Moore, Conrad L. Stanitski
Publisher: Cengage Learning
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Consider the following equation: CuSO4•5H2O + Fe → FeSO4 + Cu + 5H2O. Which substance is oxidized and which is reduced?
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Using data in Appendix 1, estimate the temperature at which Fe2O3 can be reduced to iron, using hydrogen gas as a reducing agent (assume H2O(g) is the other product).
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Aluminum is produced commercially by the electrolysis of Al2O3 in the presence of a molten salt. If a plant has a continuous capacity of 1.00 million A, what mass of aluminum can be produced in 2.00 h?
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Phosphorous acid, H3PO3, is oxidized to phosphoric acid, H3PO4, by nitric acid, which is reduced to nitrogen monoxide, NO. Write the balanced equation for this reaction.
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In an analytical determination of arsenic, a solution containing arsenious acid, H3AsO3, potassium iodide, and a small amount of starch is electrolyzed. The electrolysis produces free iodine from iodide ion, and the iodine immediately oxidizes the arsenious acid to hydrogen arsenate ion, HAsO42. I2(aq)+H3AsO3(aq)+H2O(l)2I(aq)+HAsO42(aq)+4H+(aq) When the oxidation of arsenic is complete, the free iodine combines with the starch to give a deep blue color. If, during a particular run, it takes 65.4 s for a current of 10.5 mA to give an endpoint (indicated by the blue color), how many grams of arsenic are present in the solution?
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(a) Write equations for the half-reactions that occur at the cathode and the anode when an aqueous solution of KCl is electrolyzed. Which chemical species is oxidized, and which chemical species is reduced in this reaction? (b) Predict the products formed when an aqueous solution of CsI is electrolyzed.
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