Consider the following reaction and the data provided. ​​2 HgCl2(aq) + C2O4 2-(aq) ----> 2 Cl-(aq) + 2 CO2(g) + Hg2Cl2(s) ​Exp#​​ [HgCl2] (M)​​ [C2O42-] (M) ​Rate (M/s) ​1 ​​0.164 ​​​0.15 ​​​3.2 x 10-5 ​2 ​​0.164 ​​​0.45 ​​​2.9 x 10-4 ​3 ​​0.082 ​​​0.45 ​​​1.4 x 10-4 ​4 ​​0.246 ​​​0.15 ​​​4.8 x 10-5 ​ ​​​What is the rate law? ​a) r = k[HgCl2] [C2O42-]2​​ b) r = k[HgCl2]2 [C2O42-] ​c) r = k[HgCl2] [C2O42-] ​​d) r = k[HgCl2] [C2O42-]3

Chemistry for Engineering Students
4th Edition
ISBN:9781337398909
Author:Lawrence S. Brown, Tom Holme
Publisher:Lawrence S. Brown, Tom Holme
Chapter11: Chemical Kinetics
Section: Chapter Questions
Problem 11.91PAE
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Consider the following reaction and the data provided.
​​2 HgCl2(aq) + C2O4 2-(aq) ----> 2 Cl-(aq) + 2 CO2(g) + Hg2Cl2(s)

​Exp#​​ [HgCl2] (M)​​ [C2O42-] (M) ​Rate (M/s)
​1 ​​0.164 ​​​0.15 ​​​3.2 x 10-5
​2 ​​0.164 ​​​0.45 ​​​2.9 x 10-4
​3 ​​0.082 ​​​0.45 ​​​1.4 x 10-4
​4 ​​0.246 ​​​0.15 ​​​4.8 x 10-5

​​​What is the rate law?

​a) r = k[HgCl2] [C2O42-]2​​ b) r = k[HgCl2]2 [C2O42-]
​c) r = k[HgCl2] [C2O42-] ​​d) r = k[HgCl2] [C2O42-]3

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