Consider the titration of the weak acid, benzoic acid, HC7H5O2. Its acid dissociation reaction is: HC7H5O2 (aq) + H2O (l) ↔ C7H5O2- (aq) + H3O+ (aq) A 25.00 mL sample of a solution of benzoic acid, concentration unknown, is titrated with 0.0500M NaOH solution. A plot of the titration is shown below. 1. what is the pKa (approximately) of benzoic acid? Its Ka? 2. on the plot, indicate the buffering region of the titration 3. From the pH at the equivalence point, estimate the pKb of benzoate ion (conjugate base to benzoic acid)______________ [Remember, at the equivalence point, C7H5O2- (aq) + H2O (l) ↔ HC7H5O2 (aq) + OH- (aq) ]

Chemistry for Engineering Students
4th Edition
ISBN:9781337398909
Author:Lawrence S. Brown, Tom Holme
Publisher:Lawrence S. Brown, Tom Holme
Chapter8: Molecules And Materials
Section: Chapter Questions
Problem 8.69PAE
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 Consider the titration of the weak acid, benzoic acid, HC7H5O2. Its acid dissociation reaction is:

HC7H5O2 (aq) + H2O (l) ↔ C7H5O2- (aq) + H3O+ (aq)

A 25.00 mL sample of a solution of benzoic acid, concentration unknown, is titrated with 0.0500M NaOH solution. A plot of the titration is shown below.

1. what is the pKa (approximately) of benzoic acid? Its Ka?

2. on the plot, indicate the buffering region of the titration

3. From the pH at the equivalence point, estimate the pKb of benzoate ion (conjugate base to benzoic acid)______________
[Remember, at the equivalence point, C7H5O2- (aq) + H2O (l) ↔ HC7H5O2 (aq) + OH- (aq) ]

12
10
8
4
5.0
10.0
15.0
volume of 0.0500 M NaOH
mL
Hd
Transcribed Image Text:12 10 8 4 5.0 10.0 15.0 volume of 0.0500 M NaOH mL Hd
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ISBN:
9781337398909
Author:
Lawrence S. Brown, Tom Holme
Publisher:
Cengage Learning