Draw a structural formula for the major product of the reaction shown. Br2 CH2 • Show product stereochemistry IF the reactant alkene has both carbons of the double bond within a ring. • Do not show stereochemistry in other cases. • If the reaction produces a racemic mixture, just draw one stereoisomer. B). Draw a structural formula for the major product of the reaction shown. CCH2 Br3 H20 Show product stereochemistry IF the reactant alkene has both carbons of the double bond within a ring. • Do not show stereochemistry in other cases. • If the reaction produces a racemic mixture, just draw one stereoisomer. ed C). Draw a structural formula for the major product of the reaction shown. H20 • Show product stereochemistry IF the reactant alkene has both carbons of the double bond within a ring. • Do not show stereochemistry in other cases. . If the reaction produces a racemic mixture, just draw one stereoisomer. weted

Draw a structural formula for the major product of the reaction shown. Br2 CH2 • Show product stereochemistry IF the reactant alkene has both carbons of the double bond within a ring. • Do not show stereochemistry in other cases. • If the reaction produces a racemic mixture, just draw one stereoisomer. B). Draw a structural formula for the major product of the reaction shown. CCH2 Br3 H20 Show product stereochemistry IF the reactant alkene has both carbons of the double bond within a ring. • Do not show stereochemistry in other cases. • If the reaction produces a racemic mixture, just draw one stereoisomer. ed C). Draw a structural formula for the major product of the reaction shown. H20 • Show product stereochemistry IF the reactant alkene has both carbons of the double bond within a ring. • Do not show stereochemistry in other cases. . If the reaction produces a racemic mixture, just draw one stereoisomer. weted

Organic Chemistry

9th Edition

ISBN:9781305080485

Author:John E. McMurry

Publisher:John E. McMurry

Chapter5: Stereochemistry At Tetrahedral Centers

Section5.SE: Something Extra

Problem 75AP

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When carbonyl compounds are reduced with a reagent such as LiAlH4 or NaBH4 and a new stereogenic center is formed, what will the composition of the product mixture be? Forms more of one enantiomer than another because of steric reasons around the carbonyl Forms more of one enantiomer than another depending on the temperature of the reaction Forms different products depending on the solvent used Forms a racemic mixture of the two possible enantiomers
Fill in the missing information (reactants, products, or reagents) in the following transformations. If more than one product is possible, draw structures for all products and indicate the major product. If stereoisomers are possible, draw all isomers, and indicate the major stereoisomers.
Draw the structures of the following molecules: (a) trans-l-Bromo-3-methylcyclohexane (b) cis-1, 2-Dimethylcyclobutane (c) trans-1 -tert-Butyl-2-ethylcyclohexane
Draw the products of the following reactions. If the products can exist as stereoisomers, show which stereoisomers are formed.a. cis-2-pentene + HClb. trans-2-pentene + HClc. 1-ethylcyclohexene + H2O + H2SO4d. 2,3-dimethyl-3-hexene + H2, Pd/Ce. 1,2-dimethylcyclohexene + HCl f. 1,2-dideuteriocyclohexene + H2, Pd/Cg. 3,3-dimethyl-1-pentene + Br2/CH2Cl2h. 1E2@3,4@dimethyl@3@heptene + H2, Pd/Ci. 1Z2@3,4@dimethyl@3@heptene + H2, Pd/Cj. 1@chloro@2@ethylcyclohexene + H2, Pd/C
draw the two possible carbocations that can form when this alkene reacts with a strong acid (such as HBr or H3O+). of the two structures you drew, circle the more stable carbocation
The following compounds have the same molecular formula as benzene. How many monobrominated products could each form? a. How many dibrominated products could each of the preceding compounds form? (Do not include stereoisomers.) b. How many dibrominated products could each of the compounds form if stereoisomers are included?
Draw the products of the following reactions. If the products can exist as stereoisomers, show which stereoisomers are formed. a. cis-2-pentene + HCl b. trans-2-pentene + HCl c. 1-ethylcyclohexene + H2O + H2SO4 d. 2,3-dimethyl-3-hexene + H2, Pd/C e. 1,2-dimethylcyclohexene + HCl f. 1,2-dideuteriocyclohexene + H2, Pd/C g. 3,3-dimethyl-1-pentene + Br2/CH2Cl2 h. (E)-3,4@dimethyl-3-heptene + H2, Pd/C i. (Z)-3,4-dimethyl-3-heptene + H2, Pd/C j. 1-chloro-2-ethylcyclohexene + H2 , Pd/C
4-Chloro-2-pentene has a double bond that can have either the E or the Z configuration and a stereogenic center that can have either the R or the S configuration. How many stereoisomers arepossible altogether? Draw the structure of each, and group the pairs of enantiomers.
Consider a reaction where cis-but-2-ene is treated with sO followed by NaHSO/H, O. Draw the structure of one product that is formed in the reaction, including correct stereochemistry.
help ASAP Draw the products formed when cyclohexene is treated with this reagent: NBS (aqueous DMSO)
Draw the product or products that will be obtained from the reaction of cis-2-butene and trans-2-butene with each of the following reagents. If a product can exist as stereoisomers, show which stereoisomers are formed. 1. HCl. 4.Br2 in CH2Cl2 7. H2O + H2SO4 2. BH3/THF, followed by HO-, H2O2, H2O 5. Br2 + H2O 8. CH3OH + H2SO4 3. a peroxyacid 6. H2 + Pd/C
Draw the products of the following reactions. If the products can exist as stereoisomers show what stereoisomers are formed. a. cis-2-pentene + Br2/CH2Cl2 b. trans-2-pentene + Br2/CH2Cl2 c. 1- butene + HCl d. methylcyclohexene + HBr e. trans-3-hexene + Br2/CH2Cl2 f. cis-3-hexene + Br2/CH2Cl2 g. 3,3-dimethyl-1-pentene + HBr h. cis-2-butene + HBr i. (Z)-2,3-dichloro-2-butene + H2, Pd/C j. (E)-2,3-dichloro-2-butene + H2, Pd/C k. (Z)-3,4-dimethyl-3-hexene + H2, Pd/C l. (E)-3,4-dimethyl-3-hexene + H2, Pd/C