Draw the structures (expanded) of the following compounds: d. 2,6-di-tert-butyl-4-methylphenol e. 2,4-dinitrophenol f. 2-chloro-4-ethylbenzoic acid
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A: IUPAC nomenclature follows following rules in these compounds:-
Q: H
A: ->In IUPAC naming suffix used for that functional group which has more preference.
Q: F
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A: Tollens test is done by using tollen's reagents.
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Q: Question attached
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Q: Draw a structure corresponding to following name. m-ethylaniline
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A: The details solution for this is provided below in attach image.
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- The following trisaccharide derivative is important to human health.The A ring is ?-deoxy?does structure E represent fructofuranose? explain1. Carbohydrates classification. 2. Write down the reactions: a) α,D-Glucopyranose + C2H5OH → b) D-Glucose + [Ag(NH3)2]+ → c) D-Glucopyranose + (CH3CO)2 O → d) D-Glucopyranose + CH3I → e) D-Glucose + HNO3 → f) D-Glucose + H2 → g) Lactose formation h) Sucrose hydrolysis 3. Write down the formula of β,D-galactopyranose
- The anticoagulant heparin is a polysaccharide that contains alternating residues of -D- glucuronic acid-6- sulfate and N-sulfo-D-glucosamine-6sulfate connected by (1 B 4)- glycosidic linkages. Draw a part of heparin that shows one each of the two residues.O2CCH,CH,-C-CO2 + CH2 NH3 NH3 O2CCH,CH,-C-CO2 + CH2 CH2-C-CO2 + H. phenylalanine -CO2 0,CCH,CH2—CO2 CH2-C-CO2What reagents are needed to convert (CH3CH2)3CC=CH to attachedcompound?
- Which of the following best describes the structure below A. Dextrorotatory B. Ketose C. Hexose D. Levarotatory E. Pentose F. Aldose G. TeroseSketch the Fischer projection of each Stereoisomer(R and S) of the monosaccharide glyceraldehyde, , HOCH2CHOHCHO. Prioritize the four groups attached to the stereocenter with 1 being the highest priority and 4 being the lowest priority.D-glucose and L-glucose would be expected to show differences in which of the followingp roperties? (Answer the items as dif erent or not different) a. Solubility in an achiral solvent b. Density c. Melting point d. Solubility in a chiral solvent e. Freezing point f. Reaction with ethanol (achiral compound) g. Reaction with (+)-lactic acid (chiral compound)
- Draw the structure of alpha-d-glucopyranose in straight chain cyclic, Haworth and cyclohexane-chair format. Draw the structures of two aldohexoses which are diastereomers but not epimersDraw the tetrapeptide represented by HLQS at physiological pH (pH=7.4), Include proper stereochemistryWhen some sugars dissolve in water they spontaneously undergo changes in optical rotation called mutarrotation. The Mutarrotation of D-glucopyranose is catalyzed by acid and bases. 2-Hydroxypyridine is a more effective catalyst than phenol and pyridine for this reaction because: a.Both oxygen and N in 2-hydroxypyridine act as bases increasing the rapid interconversion of sugar b. The OH of 2-hydroxypyridine serves as the base while the current N as the acid. c. 2-hydroxypyridine acts both as a base to remove the proton from the hydroxyl group in the hemiacetal and as an acid to provide a proton to the oxygen in the hemiacetal. d.Phenol and pyridine are very expensive.