Identify the species oxidized, the species reduced, the oxidizing agent and the reducing agent in the following electron-transfer reaction.F2(g) + Cd(s) –→ 2F°(aq) + Cd²*(*(aq)species oxidizedspecies reducedoxidizing agentreducing agentAs the reaction proceeds, electrons are transferred fromto

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Chemistry: The Molecular Science

5th Edition

ISBN:9781285199047

Author:John W. Moore, Conrad L. Stanitski

Publisher:John W. Moore, Conrad L. Stanitski

Chapter19: The Chemistry Of The Main-group Elements

Section: Chapter Questions

Problem 44QRT

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The iron content of hemoglobin is determined by destroying the hemoglobin molecule and producing small water-soluble ions and molecules. The iron in the aqueous solution is reduced to iron(II) ion and then titrated against potassium permanganate. In the titration, iron(ll) is oxidized to iron(III) and permanganate is reduced to manganese(II) ion. A 5.00-g sample of hemoglobin requires 32.3 mL of a 0.002100 M solution of potassium permanganate. The reaction with permanganate ion is MnO4(aq)+8H+(aq)+5Fe2+(aq)Mn2+(aq)+5Fe3+(aq)+4H2O What is the mass percent of iron in hemoglobin?
One of the few industrial-scale processes that produce organic compounds electrochemically is used by the Monsanto Company to produce1,4-dicyanobutane. The reduction reaction is 2CH2CHCH+2H++2eNC(CH2)4CN The NC(CH2)4CN is then chemically reduced using hydrogen gas to H2N(CH2)6NH2, which is used in the production of nylon. What current must be used to produce 150.kg NC(CH2)4CN per hour?
Bromine is obtained from sea water by the following redox reaction: Cl2(g) + 2 NaBr(aq) 2 NaCl(aq) + Br2() (a) What has been oxidized? What has been reduced? (b) Identify the oxidizing and reducing agents.
The carbon dioxide exhaled in the breath of astronauts is often removed from the spacecraft by reaction with lithium hydroxide 2LiOH(s)+CO2(g)Li2CO3(s)+H2O(l) Estimate the grams of lithium hydroxide required per astronaut per day. Assume that each astronaut requires 2.50 103 kcal of energy per day. Further assume that this energy can be equated to the heat of combustion of a quantity of glucose, C6H12O6, to CO2(g) and H2O(l). From the amount of glucose required to give 2.50 103 kcal of heat, calculate the amount of CO2 produced and hence the amount of LiOH required. The H for glucose(s) is 1273 kJ/mol.
Write balanced net ionic equations for the following reactions in acid solution. (a) Liquid hydrazine reacts with an aqueous solution of sodium bromate. Nitrogen gas and bromide ions are formed. (b) Solid phosphorus (P4) reacts with an aqueous solution of nitrate to form nitrogen oxide gas and dihydrogen phosphate (H2PO4-) ions. (c) Aqueous solutions of potassium sulfite and potassium permanganate react. Sulfate and manganese(II) ions are formed.
. To obtain useful electrical energy from an oxidation-reduction process, we must set up the reaction in such a way that the Oxidation half-reaction and the reduction half-reaction are physically one _____another.
An electrolytic cell is set up with Cd(s) in Cd(NO3)2(aq) and Zn(s) in Zn(NO3)2(aq). Initially both electrodesweigh 5.00 g. After running the cell for several hours theelectrode in the left compartment weighs 4.75 g. (a) Which electrode is in the left compartment? (b) Does the mass of the electrode in the right compartmentincrease, decrease, or stay the same? If the masschanges, what is the new mass? (c) Does the volume of the electrode in the right compartment increase, decrease, or stay the same? If the volumechanges, what is the new volume? (The density of Cd is8.65 g/cm3.)
An aqueous solution of an unknown salt of gold is electrolyzed by a current of 2.75 amps for 3.39 hours. The electroplating is carried out with an efficiency of 93.0%, resulting in a deposit of 21.221 g of gold. a How many faradays are required to deposit the gold? b What is the charge on the gold ions (based on your calculations)?
Gold can be dissolved from gold-bearing rock by treating the rock with sodium cyanide in the presence of oxygen. 4 Au(s) + 8 NaCN(aq) + O2(g) + 2 H2O() 4 NaAu(CN)2(aq) + 4 NaOH(aq) (a) Name the oxidizing and reducing agents in this reaction. What has been oxidized, and what has been reduced? (b) If you have exactly one metric ton (1 metric ton = 1000 kg) of gold-bearing rock, what volume of 0.075 M NaCN, in liters, do you need to extract the gold if the rock is 0.019% gold?
Balance the following redox reactions occurring in basic aqueous solution. Identify the species being oxidized, species being reduced, the oxidizing agent, and the reducing agent. ClO- (aq)+Cr(OH)4- > CrO4- + Cl-
Consider the following balanced redox reaction: 16H+(aq) + 2MnO4-(aq) + 10Cl-(aq) → 2Mn2+(aq) + 5Cl2(g) + 8H2O(l)(a) Which species is being oxidized?(b) Which species is being reduced?(c) Which species is the oxidizing agent?(d) Which species is the reducing agent?(e) From which species to which does electron transfer occur?(f ) Write the balanced molecular equation, with K+ and SO42- as the spectator ions.
Consider the following balanced redox reaction:2CrO₂⁻(aq) +2H₂O(l)+6ClO⁻(aq)→ 2CrO₄²⁻(aq) +3Cl₂(g) +4OH⁻(aq)(a) Which species is being oxidized?(b) Which species is being reduced?(c) Which species is the oxidizing agent?(d) Which species is the reducing agent?(e) From which species to which does electron transfer occur?(f) Write the balanced molecular equation, with Naas the spec-tator ion.

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entify the species oxidized, the species reduced, the oxidizing agent and the reducing agent in the following electron-transfer rea F2(g) + Cd(s) → 2F(aq) + Cd²*(aq) species oxidized species reduced oxidizing agent reducing agent s the reaction proceeds, electrons are transferred from to