Excess solid Na₂CO₃ is added to a solution containing 0.400 M (each) Mg²⁺ and Zn²⁺ ions. Ksp for MgCO₃ is 3.50 × 10⁻⁸ and Ksp for ZnCO₃ is 1.00 × 10⁻¹⁰. ZnCO₃, with the smaller Ksp, will be the least soluble and will begin precipitating first. What will be the [Zn²⁺] concentration when MgCO₃ just begins to precipitate? (Assume no volume change upon addition of the solid Na₂CO₃)

Chemistry & Chemical Reactivity
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ISBN:9781133949640
Author:John C. Kotz, Paul M. Treichel, John Townsend, David Treichel
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Chapter21: The Chemistry Of The Main Group Elements
Section21.5: The Alkaline Earth Elements, Group 2a
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Excess solid Na₂CO₃ is added to a solution containing 0.400 M (each) Mg²⁺ and Zn²⁺ ions. Ksp for MgCO₃ is 3.50 × 10⁻⁸ and Ksp for ZnCO₃ is 1.00 × 10⁻¹⁰. ZnCO₃, with the smaller Ksp, will be the least soluble and will begin precipitating first. What will be the [Zn²⁺] concentration when MgCO₃ just begins to precipitate? (Assume no volume change upon addition of the solid Na₂CO₃).
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