Explain using mechanisms the regiochemistry and stereochemistry observed for the following reactions

Organic Chemistry
9th Edition
ISBN:9781305080485
Author:John E. McMurry
Publisher:John E. McMurry
Chapter30: Orbitals And Organic Chemistry: Pericyclic Reactions
Section30.7: Sigmatropic Rearrangements
Problem 7P
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Explain using mechanisms the regiochemistry and stereochemistry observed for the
following reactions
D
Ar
H
Ar
C(CH3)3
DBr Ar
Ar
DBr
C(CH3)3
C(CH3)3
H
C(CH3)3
H
H
Br
Br
Transcribed Image Text:Explain using mechanisms the regiochemistry and stereochemistry observed for the following reactions D Ar H Ar C(CH3)3 DBr Ar Ar DBr C(CH3)3 C(CH3)3 H C(CH3)3 H H Br Br
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