Number 4 answer? 3. A 400-mL solutronin an insulated bottle. A 200-mL solution Of 0.400 M Ca(OH)2 also at30.5°C was added to the insulated bottle. After mixing, thetemperature rose to 31.2°C. Assuming that the densities andspecific heats of the solutions are the same as that of water (Cwater= 4.18 J g1°C 1), what is the heat evolved in the neutralization of1.00 mol of HA?Expt 54. Draw a bomb calorimeter and label its parts. Briefly describe howona bomb calorimeter works.ns5. What is the difference between a coffee cup calorimeter and abomb calorimeter, in terms of the parameters it can measure?6. A sample of 1.550 g of liquid hexane (C,H14) undergoescombustion in a bomb calorimeter, and the temperature rises from25.87°C to 38.13° Find DEn for the reaction in kJ/mol hexane. Theheat capacity of the bomb calorimeter, determined in a separateendaretexperiment, is 5.73 kJ/°C.ve7 The comhunti

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Answered: Expt 5 4. Draw a bomb calorimeter and…

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Expt 5 4. Draw a bomb calorimeter and label its parts. Briefly describe how a bomb calorimeter works.

Chemistry: Principles and Reactions

8th Edition

ISBN:9781305079373

Author:William L. Masterton, Cecile N. Hurley

Publisher:William L. Masterton, Cecile N. Hurley

Chapter8: Thermochemistry

Section: Chapter Questions

Problem 12QAP: The heat of neutralization, Hneut, can be defined as the amount of heat released (or absorbed), q,...

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Magnesium sulfate is often used in first-aid hot packs, giving off heat when dissolved in water. A coffee-cup calorimeter at 25C contains 15.0 mL of water at 25C. A 2.00-g sample of MgSO4 is dissolved in the water and 1.51 kJ of heat are evolved. (You can make the following assumptions about the solution: volume=15.0 mL, density=1.00 g/mL, specific heat=4.18J/gC.) (a) Write a balanced equation for the solution process. (b) Is the process exothermic? (c) What is qH2O? (d) What is the final temperature of the solution? (e) What are the initial and final temperatures in F?
Sodium chloride is added in cooking to enhance the flavor of food. When 10.00 g of NaCl are dissolved in 200.0 mL of water at 25.0C in a coffee-cup calorimeter, 669 J of heat are absorbed. (You can make the following assumptions about the solution: volume =200.0 mL, density =1.00 g/mL, specific heat =4.18J/gC) (a) Is the solution process exothermic? (b) What is qH2O? (c) What is the final temperature of the solution?
How much heat is produced when loo mL of 0.250 M HCl (density, 1.00 g/mL) and 200 mL of 0.150 M NaOH (density, 1.00 g/mL) are mixed? HCl(aq)+NaO(aq)NaCl(aq)+H2O(l)H298=58kJ If both solutions are at the same temperature and the heat capacity of the products is 4.19 J/g C, how much will the temperature increase? What assumption did you make in your calculation?
ou place hot metal into a beaker of cold water. ol type='a'> Eventually what is true about the temperature of the metal compared to that of the water? Explain why this is true. i>Label this process as endothermic or exothermic if we consider the system to be the metal. Explain. the water. Explain.
In a coffee-cup calorimeter, 100.0 mL of 1.0 M NaOH and 100.0 mL of 1.0 M HCI are mixed. Both solutions were originally at 24.6C. After the reaction, the final temperature is 31.3C. Assuming that all the solutions have a density of 1.0 g/cm3 and a specific heat capacity of 4.18 J/Cg, calculate the enthalpy change for the neutralization of HCl by NaOH. Assume that no heat is lost to the surroundings or to the calorimeter.
Would the amount of heat absorbed by the dissolution in Example 5.6 appear greater, lesser, or remain the same if the heat capacity of the calorimeter were taken into account? Explain your answer.
Benzoic acid, C6H5COOH, is a common standard used in bomb calorimeters, which maintain a constant volume. If 1.20 g of benzoic acid gives off 31, 723 J of energy when burned in the presence of excess oxygen and in a water bath having a temperature of 24.6 C, calculate q, w, H, and U for the reaction.
The heat of neutralization, Hneut, can be defined as the amount of heat released (or absorbed), q, per mole of acid (or base) neutralized. Hneut for nitric acid is -52 kJ/mol HNO3. At 27.3C, 50.00 mL of 0.743M HNO3 is neutralized by 1.00 M Sr(OH)2 in a coffee-cup calorimeter. (a) How many mL of Sr(OH)2 were used in the neutralization? (b) What is the final temperature of the resulting solution? (Use the assumptions in Question 11.)
A 21.3-mL sample of 0.977 M NaOH is mixed with 29.5 mL of 0.918 M HCl in a coffee-cup calorimeter (see Section 6.6 of your text for a description of a coffee-cup calorimeter). The enthalpy of the reaction, written with the lowest whole-number coefficients, is 55.8 kJ. Both solutions are at 19.6C prior to mixing and reacting. What is the final temperature of the reaction mixture? When solving this problem, assume that no heat is lost from the calorimeter to the surroundings, the density of all solutions is 1.00 g/mL, the specific heat of all solutions is the same as that of water, and volumes are additive.
On complete combustion at constant pressure, a 1.00-L sample of a gaseous mixture at 0C and 1.00 atm (STP) evolves 75.65 kJ of heat. If the gas is a mixture of ethane (C2H6) and propane (C3H8), what is the mole fraction of ethane in the mixture?
Magnesium sulfate is often used in first-aid hot packs, giving off heat when dissolved in water. A coffee-cup calorimeter at 25°C contains 15.0 mL of water at 25°C. A 2.00-g sample of MgSO4 is dissolved in the water and 1.51 kJ of heat are evolved. (You can make the following assumptions about the solution: volume = 15.0 mL, density = 1.00 g/mL, specific heat 5 4.18 J/g · °C.)(a) Write a balanced equation for the solution process.(b) What is qH2O?(c) What is the final temperature of the solution?
80.0 mL of isopropanol (d = 0.825 g/cm3) initially at 5.00°C was added to 60.0 mL of ethanol (d = 0.795 g/cm3) initially at 27.5°C. If the specific heat of ethanol is 2.46 J/g. oC and the specific heat of isopropanol is 2.68 J/g. oC), what was the final temperature of the solution once the liquids were mixed?

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