Following is an equation for the reaction of diisopropyl ether and oxygen to form a hydroperoxide. HO + O2 Diisopropyl ether A hydroperoxide Formation of an ether hydroperoxide is a radical chain reaction.

Following is an equation for the reaction of diisopropyl ether and oxygen to form a hydroperoxide. HO + O2 Diisopropyl ether A hydroperoxide Formation of an ether hydroperoxide is a radical chain reaction.

Organic Chemistry

9th Edition

ISBN:9781305080485

Author:John E. McMurry

Publisher:John E. McMurry

Chapter19: Aldehydes And Ketones: Nucleophilic Addition Reactions

Section19.SE: Something Extra

Problem 28VC

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Question

Account for the fact that hydroperoxidation of ethers is regioselective
(i.e., reaction occurs preferentially at a carbon adjacent to the ether oxygen).

Following is an equation for the reaction of diisopropyl ether and oxygen to form a
hydroperoxide.
HO
+ O2
Diisopropyl ether
A hydroperoxide
Formation of an ether hydroperoxide is a radical chain reaction.

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