Following is the mass spectrum of 1,2-dichloroethane. Propose a structural formula for the cation of m/2 63. X? D 100- 80- 60- 40- 20 10 20 60 m/2 . CI can represent either or C • Br can represent either 79Br or 18 . In cases where there is more than one answer, just draw one You do not have to include radical electrons in your answer. 70 MO 100 99 H₂C-CH₂ MW-98 Spectrs images are reproduced by permission from Signa-Aldrich and the National Institute of Advanced Industrial Science and Technology (Soesweb 2/7/09, 2/23/09, 3/10/09) 100 110 120 1.00, 8/26/S

Organic Chemistry
8th Edition
ISBN:9781305580350
Author:William H. Brown, Brent L. Iverson, Eric Anslyn, Christopher S. Foote
Publisher:William H. Brown, Brent L. Iverson, Eric Anslyn, Christopher S. Foote
Chapter14: Mass Spectrometry
Section: Chapter Questions
Problem 14.29P
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Following is the mass spectrum of 1,2-dichloroethane. Propose a structural formula for the cation of m/2 63.
2
100
80
60
40-
20.
0
10
20
30
40
50
60
62
24
m/z
. In cases where there is more than one answer, just draw one.
You do not have to include radical electrons in your answer.
• Cl can represent either 35Cl or 37C.
• Br can represent either 79Br or 818r.
70
80
M (98) 100
90
99
H₂C-CH₂
MW-98
Spectra images are reproduced by permission from Sigma-Aldrich and the National Institute of Advanced Industrial Science and Technology (Sonsweb: http://mob01buse antodb. 11/26/05
2/7/09, 2/13/09, 3/10/09)
100 110 120
Transcribed Image Text:Following is the mass spectrum of 1,2-dichloroethane. Propose a structural formula for the cation of m/2 63. 2 100 80 60 40- 20. 0 10 20 30 40 50 60 62 24 m/z . In cases where there is more than one answer, just draw one. You do not have to include radical electrons in your answer. • Cl can represent either 35Cl or 37C. • Br can represent either 79Br or 818r. 70 80 M (98) 100 90 99 H₂C-CH₂ MW-98 Spectra images are reproduced by permission from Sigma-Aldrich and the National Institute of Advanced Industrial Science and Technology (Sonsweb: http://mob01buse antodb. 11/26/05 2/7/09, 2/13/09, 3/10/09) 100 110 120
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