For an SN1 reaction with AgNO3 in ethanol Substrate Write equations involved 1-chlorobutane 1-bromobutane 2-chloro-2-methylpropane 2-chlorobutane 2-bromobutane
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For an SN1 reaction with AgNO3 in ethanol
| Substrate |
Write equations involved
|
| 1-chlorobutane | |
| 1-bromobutane | |
|
2-chloro-2-methylpropane |
|
| 2-chlorobutane | |
| 2-bromobutane |
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- tert-butyl chloride (2-chloro-2-methylpropane) from tert- butyl alcohol (tert-butanol) using an acid catalyzed dehydration reaction Physical Constants Compound Mol. Wt (g/mol) Density (g/mL) b.p. (°C) m.p. (°C) 2-Methyl-2-propanol 74.12 0.786 82 25 2-Chloro-2- methylpropane 92.57 0.851 51 -25 Hydrochloric acid 37% soln in H2O 1.18 -85 -26 12.0ml of t-butyl alcohol, with 25.0ml 12.0M HCl, 12ml of water, 12ml of saturated aqueous sodium bicarbonate, 12ml of saturated aqueous sodium chloride, magnesium sulfate Typically yield 6.34g How would I calculate theoretical and percent yield for the reaction ? Please and thank you!tert-butyl chloride (2-chloro-2-methylpropane) from tert- butyl alcohol (tert-butanol) using an acid catalyzed dehydration reaction Physical Constants Compound Mol. Wt (g/mol) Density (g/mL) b.p. (°C) m.p. (°C) 2-Methyl-2-propanol 74.12 0.786 82 25 2-Chloro-2- methylpropane 92.57 0.851 51 -25 Hydrochloric acid 37% soln in H2O 1.18 -85 -26 12.0ml of t-butyl alcohol, with 25.0ml 12.0M HCl, 12ml of water, 12ml of saturated aqueous sodium bicarbonate, 12ml of saturated aqueous sodium chloride, magnesium sulfate 1 (CH3)COH + 1 H3O^+ Cl^- -> 1 (CH3)3CCl + 2 H2O Typically yield 6.34g Why is the percent yield be lower than expected? 53.9% .. Is it due to evaporation? Is it not the major product? If this reaction was with 2-butanol/HCl instead of tert butanol, how would I obtain the products/mechanism, and determine major products? Thank you!!tert-butyl chloride (2-chloro-2-methylpropane) from tert- butyl alcohol (tert-butanol) using an acid catalyzed dehydration reaction Physical Constants Compound Mol. Wt (g/mol) Density (g/mL) b.p. (°C) m.p. (°C) 2-Methyl-2-propanol 74.12 0.786 82 25 2-Chloro-2- methylpropane 92.57 0.851 51 -25 Hydrochloric acid 37% soln in H2O 1.18 -85 -26 12.0ml of t-butyl alcohol, with 25.0ml 12.0M HCl, 12ml of water, 12ml of saturated aqueous sodium bicarbonate, 12ml of saturated aqueous sodium chloride, magnesium sulfate 1 (CH3)COH + 1 H3O^+ Cl^- -> 1 (CH3)3CCl + 2 H2O Typically yield 6.34g How would I calculate theoretical and percent yield for the reaction ? Please and thank you!
- tert-butyl chloride (2-chloro-2-methylpropane) from tert- butyl alcohol (tert-butanol) using an acid catalyzed dehydration reaction Physical Constants Compound Mol. Wt (g/mol) Density (g/mL) b.p. (°C) m.p. (°C) 2-Methyl-2-propanol 74.12 0.786 82 25 2-Chloro-2- methylpropane 92.57 0.851 51 -25 Hydrochloric acid 37% soln in H2O 1.18 -85 -26 12.0ml of t-butyl alcohol, with 25.0ml 12.0M HCl, 12ml of water, 12ml of saturated aqueous sodium bicarbonate, 12ml of saturated aqueous sodium chloride, magnesium sulfate 1 (CH3)COH + 1 H3O^+ Cl^- -> 1 (CH3)3CCl + 2 H2O Typically yield 6.34g Why is the percent yield be lower than expected? 53.9% .. Is it due to evaporation? What is the major product of this reaction? isobutene or t-butylchloride? If this reaction was with 2-butanol/HCl instead of tert butanol, how would I obtain the products/mechanism (SN2?), and determine major products? If sn2, why? Thank you!! This was…(i) State one use each of DDT and iodoform.(ii) Which compound in the following couples will react faster in SN2 displacement and why?(a) 1-bromopentane or 2-bromopentane(b) l-bromo-2-methylbutane or 2-bromo-2-methylbutane.Case: In an attempt to synthesize compound 1a, the researchers mixed benzaldehyde, dimedone (IUPAC: 5,5-dimethylcyclohexane-1,3-dione), and 3-amino-1,2,4-triazole in ethanol as the solvent. A catalyst that acts both as a Bronsted-Lowry and as a Lewis acid was also added to aid the reaction. Benzaldehyde and dimedone reacts first with each other, then the resulting intermediate eventually reacts with the aminotriazole to form 1a. 1. Explain how benzaldehyde and dimedone reacts with each other, and then with the aminotriazole to form compound 1a in the presence of an acid catalyst. Provide a detailed reaction mechanism.
- In which of the statements given below, the event is not an oxidation reaction? A. Product formation as a result of the reaction of benzoine with nitric acid B. Formation of the product as a result of the reaction of 2-propene at KMnO4 / Basic ambient temperature C. Formation of the product as a result of the reaction of 2-propene in KMnO4 / Basic medium cold D. CH3CH2OH + KMnO4 → CH3COOH E. Reaction of an alkyl halide with ammoniaShow the electron-flow mechanism of the synthetic schemes (R-Salsolinol) of the picture below. This involves predicting major and by-products using electronic and structural effects. The arrow push mechanism must be shown.(True/False) The use of sodium iodide in acetone promotes SN2 mechanism for alkyl halide resulting in the formation of insoluble salts in the mixture. (True/false) For alkyl halides, we use a solution of AgNO3 in ethanol because ethanol is a polar protic solvent suited for SN1 mechanism. (True/False) 1-bromobutane, 2-bromobutane (aka sec-butyl bromide), tert-butyl bromide, benzyl chloride, and bromobenzene will not form precipitates in either 1M NaI/acetone and 2% AgNO3/EtOH.
- What is the energy diagram of the following Sn1 reaction. 2-chloro-2-methylpropane + H2O -> 2-methylpropan-2-ol + HCl write the rate law equationFill in the fields (reagent or products) left blank in the reaction below.Show the catalytic cycle for the oxidation of 1-phenylethanol and do not use a generic substrate ROH using RuCl2(PPh3)3 as the catalyst.
