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- For the reaction N2 (g) + 3H2(g) --> 2 NH3 (g), (a) what is the reaction Gibbs free energy at equilibrium? ....... J/mol The equilibrium constant of the reaction N2 (g) + 3H2(g) --> 2 NH3 (g) at 68 oC is Keq = 401,568. (b) What is the standard reaction Gibbs energy of this reaction?.....J/mol4.32) Certain bacteria in soil obtain the necessary energy for growth by oxidizing nitrite to nitrate: 2NO2- (aq) + O2 (g) —-> 2NO3- Given that the standard Gibbs energies of formation of NO2- and NO3- are -34.6 kJ mol-1 and -110.5 kJ mol-1, respectively, Calculate the amount of Gibbs energy released when 1 mole of NO2- is oxidized to 1 mole of NO3-.a)For the reaction given in Part A, how much heat is absorbed when 3.10 molmol of AA reacts? Express your answer numerically in kilojoules. b)For the reaction in Part A, ΔrS∘=25.0 J K−1 mol−1ΔrS∘=25.0 J K−1 mol−1. What is the standard Gibbs energy of reaction at 281 KK , ΔrG∘ (281K)ΔrG∘ (281K)? Express your answer numerically in kJ mol−1kJ mol−1.
- Calculate the Gibbs energy and equilibrium constant for the chemical reaction at a temperature of 298.15 K. Hg2Cl2(s) → → 2 Hg(l) +Cl2(g). Does the value of the equilibrium constant you calculated describe your understanding of the spontaneity of the reaction in the direction of the arrow?For the reaction N2 (g) + 3H2(g) --> 2 NH3 (g), (a) what is the reaction Gibbs free energy at equilibrium in J/mol? The equilibrium constant of the reaction N2 (g) + 3H2(g) --> 2 NH3 (g) at 81 oC is Keq = 478,789. (b) What is the standard reaction Gibbs energy of this reaction in J/mol?Define Chemical potential μ= μi+ + μi-, in terms of ion activity coefficients-Express the mean activity coefficient of the ions of the solution of CaCl2 in terms of the activity coefficients of the individual ions.
- Sodium acetate, NaCH3CO2, of mass 7.4 g is used to prepare 250 cm3 of aqueous solution. What is the pH of the solution?The standard reaction Gibbs energy for the reactionH2(g) + (1)/(2)O2(g) → H2O(I) is -237.13 kJ mol-1 at 25 °c. Determine the equilibrium constant in terms of concentration, Kc, at this temperature.What would be the KPs value of Al(OH)3, considering that its solubility is 2,5 x 10^-8 mol/L?
- Calculate the standard Gibbs energy change for the following reaction at 298 K H2(g) + Cl2(g) ® 2HCl(g) [DfHo = –92.3 kJ mol–1 for HCl; S in J K–1 mol–1 is 131, 223, and 187 for H2, Cl2 and HCl, respectively].Thermodynamic data can be used to predict the solubilities of compounds that would be very difficult to measure directly. Calculate the solubility of mercury(ll) chloride in water at 25 °C from standard Gibbs energies of formation.What is the solubility of CO2 in a soft drink (which is mainly water) that was bottled under a CO2 pressure of 4.6 X 105 Pa?