From the following data, determine the rate law and rate constant [NO] (M) [H2] (M) Rate (M/min) 1 0.01 0.01 0.006 2 0.02 0.03 0.144 3 0.01 0.02 0.012 From the following reaction rates observed in 4 experiments, derive the rate law for the reaction Run
From the following data, determine the rate law and rate constant [NO] (M) [H2] (M) Rate (M/min) 1 0.01 0.01 0.006 2 0.02 0.03 0.144 3 0.01 0.02 0.012 From the following reaction rates observed in 4 experiments, derive the rate law for the reaction Run
Introduction to Chemical Engineering Thermodynamics
8th Edition
ISBN:9781259696527
Author:J.M. Smith Termodinamica en ingenieria quimica, Hendrick C Van Ness, Michael Abbott, Mark Swihart
Publisher:J.M. Smith Termodinamica en ingenieria quimica, Hendrick C Van Ness, Michael Abbott, Mark Swihart
Chapter1: Introduction
Section: Chapter Questions
Problem 1.1P
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![1
From the following data, determine the rate law and rate constant
[NO] (M)
[H2] (M) Rate (M/min)
0.01
0.01
0.006
0.03
0.144
3
0.02
0.012
4. From the following reaction rates observed in 4 experiments, derive the rate law for the reaction
Run
پھر
1
2
A+B+C products
where reaction rates are measured as soon as the reactants are mixed.
1
0.02
0.01
The decomposition of hydrogen iodide has rate constants of 9.51 x10 L/mol.s at 500.0 K and
1.10 x 105 L/mol.s at 600.0 K. Find Ea.
Expt 1
2 3
4
0.100 0.200 0.200 0.100
[A].
[B] 0.100 0.100 0.300 0.100
[C]
0.100 0.100 0,100 0.400
rate
0.100 0.800 7.200 0.400
6. in an aikuiine solution, peroxydisuifete oxidizes sulfite to yield sulfate,
S₂0² + SO² + 2 OH3 SO² + H₂O.
The following mechanism has been proposed:
i
S₂0² +SO₁²-k₁S₂0₁²+ So₂²-
S₂0₂² + H₂O -- 2 SO² + 2 H+
H+ + OH -k→ H₂O (fast equilibrium to be discussed)
iii
Steady-state approximation follows these steps:
What is or are the intermediates I?
Use which step to give the rate law that may involve [1]?
Express the rates of producing and consuming intermediate(s)
Express [1] of intermediate(s) in terms of [Reactants]
Derive the rate law in terms of [Reactants]
Discuss value and units of the rate constant?
CH 1207 COURSE INSTRUCTOR 2021/2022: MORRIS HIJI
Infinix NOTE 8i](/v2/_next/image?url=https%3A%2F%2Fcontent.bartleby.com%2Fqna-images%2Fquestion%2F5b64c843-4eeb-4cc8-b4ab-15c174f48ac5%2F3b024bb5-f8e5-4ef8-87e0-59c880a8f157%2Fonyuavb_processed.jpeg&w=3840&q=75)
Transcribed Image Text:1
From the following data, determine the rate law and rate constant
[NO] (M)
[H2] (M) Rate (M/min)
0.01
0.01
0.006
0.03
0.144
3
0.02
0.012
4. From the following reaction rates observed in 4 experiments, derive the rate law for the reaction
Run
پھر
1
2
A+B+C products
where reaction rates are measured as soon as the reactants are mixed.
1
0.02
0.01
The decomposition of hydrogen iodide has rate constants of 9.51 x10 L/mol.s at 500.0 K and
1.10 x 105 L/mol.s at 600.0 K. Find Ea.
Expt 1
2 3
4
0.100 0.200 0.200 0.100
[A].
[B] 0.100 0.100 0.300 0.100
[C]
0.100 0.100 0,100 0.400
rate
0.100 0.800 7.200 0.400
6. in an aikuiine solution, peroxydisuifete oxidizes sulfite to yield sulfate,
S₂0² + SO² + 2 OH3 SO² + H₂O.
The following mechanism has been proposed:
i
S₂0² +SO₁²-k₁S₂0₁²+ So₂²-
S₂0₂² + H₂O -- 2 SO² + 2 H+
H+ + OH -k→ H₂O (fast equilibrium to be discussed)
iii
Steady-state approximation follows these steps:
What is or are the intermediates I?
Use which step to give the rate law that may involve [1]?
Express the rates of producing and consuming intermediate(s)
Express [1] of intermediate(s) in terms of [Reactants]
Derive the rate law in terms of [Reactants]
Discuss value and units of the rate constant?
CH 1207 COURSE INSTRUCTOR 2021/2022: MORRIS HIJI
Infinix NOTE 8i
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