/ Give the products of each of the following reactions:1- CH3Mgbr2- H2О1-Me2-+ CH3OH → ?OCH3HCI3-H2O4- CH3CH2 = 0+ H2NNHNO2 ? + ?NO21- LIAIH45-2- H20Me6-NHMEHCI+ C2HSOH? + ?8/ Propose a mechanism for each of the following:1- CH3 - C - NHCH3 +LIAIH4 an amine.an amideNH2NH22-MeH2O113- R- C N: R-C - OH

Depending on the reactant the reaction mechanism changes and the product also changes .

/ Give the products of each of the following reactions : 1- CH3Mgbr 2- H20 1- Me + CH3OH ? OCH3 HCI 3- H2O 4- CH3CH2 = 0 + H2NNH NO2 ? + ? NO2 O 1- LIAIH4 5- 2- H20 Me 6- NHMe HCI + C2HSOH ? + ? 8/ Propose a mechanism for each of the following: 1- CH3 - C - NHCH3 + LIAIH4 an amine. an amide NH2 NH2 2- Me o H2O 11 3- R- CEN: R-C OH 2-

/ Give the products of each of the following reactions : 1- CH3Mgbr 2- H20 1- Me + CH3OH ? OCH3 HCI 3- H2O 4- CH3CH2 = 0 + H2NNH NO2 ? + ? NO2 O 1- LIAIH4 5- 2- H20 Me 6- NHMe HCI + C2HSOH ? + ? 8/ Propose a mechanism for each of the following: 1- CH3 - C - NHCH3 + LIAIH4 an amine. an amide NH2 NH2 2- Me o H2O 11 3- R- CEN: R-C OH 2-

Organic Chemistry

9th Edition

ISBN:9781305080485

Author:John E. McMurry

Publisher:John E. McMurry

Chapter25: Biomolecules: Carbohydrates

Section25.SE: Something Extra

Problem 49AP

See similar textbooks

Similar questions

7/ Give the products of each of the following reactions: 1- 1- CH3Mgbr ? 2- H20 Me 2- + CH3OH -→ OCH3 HCI 3- ? H2O NO2 ? + ? NO2 4- CH3CH2 =0+ H2NNH 1- LIAIH4 5- 2- H20 Me NHME HCI + C2H$OH + ? + ? 8/ Propose a mechanism for each of the following : 1- CH3 - C - NHCH3 + LIAIH4 → an amine an amide NH2 NH2 2- Me H2O 3- R- C N: R-C -OH
10. Propose a mechanism for the benzoin condensation, which is specifically catalyzed by cya- nide: () 2Ar-C-H CH₂-C-CH₂-C-H CN O OH Ar-C-C-Ar H 11. Propose a mechanism for the following transformation: COOC H. Nall COOC₂H₂ H₂C-CH-PPh,Br H₂C coỌC H COOCH, + Phụ P=0
8-6 Propose a mechanism for the following reaction.105 CH3 CH3 H;C- CH3 HC, PMe, (2 equiv.) H,C "CH3 PHCH, "CH3 PMey H,C H,C Me P How to draw the mechanism?
Which reactlon gives the Indicated product as major oe? CI OCH3 CH,ONa + NacI a) KOC(CH3)3 + KCI + (CH3)COH b) CH3 Br CH3 NH2 NANH2 + NaBr c) OH ONa NaOH + H20 (P Br NASH + NaBr + H2S
1. Propose a mechanism for the following transformation: R COOH (1) H₂C-O, (C₂H₂)₂NH (2) H₂O, acetate buffer R CH₂
1 20 What sequence of reactions will accomplish the following synthetic transformation? & A CO,H LiAlH4 B LiAlH4 H/H₂O H/H₂O CrO 3/Ht D HO-CH₂-CH₂-OH, H+ C NaBH4 HO-CH,CH)-OH, H* -CH₂-OH CH3-CH₂-OH, H+ LiAlH4 H₂O/OH H₂O2 H/H₂O OH (aq)
+ hv H.2 + Propose a mechanism for the reaction that fully accounts for the formation of both products.
Propose a mechanism for the reaction shown below. а) CI OH ONH2 + CI Нeat NO2 NO2 b) NO2 HNO3 H2SO4
What is the mechanism of the following reaction? EN e : Nu Nu + N₂ + CI A two-step mechanism involving the formation of a benzyne intermediate A multistep mechanism involving bonding of nucleophile to -N₂(+), followed by rearrangement, then loss of N₂ leaving group. X A two-step process, where a 6-member ring carbanion intermediate is formed in first step, followed by ejection of CI(-) in second step. SN2 mechanism, where Nu:(-) replaces -N₂ leaving group in a single step An SN1 mechanism in which the diazonium ion forms a phenyl cation in the first step (N₂ is leaving group), followed by attachment of Nu: (-) to the benzene ring.
Propose a mechanism for the following conversion ОН + H30
10. Propose the mechanism for the following transformation: omy-of ww
2. The following transformation takes place when a strong base such as methoxide is used. Please propose a reasonable mechanism for this reaction. MeO₂C CO₂Me MeO₂C. + H₁ gl H 3. Please draw a mechanism to explain the following transformation. CO₂Me OMe NaH CO₂Me O: MeO₂C MeO₂C O: MeO₂C H A CO₂Me CO₂Me :0 CO₂Me