Give the reaction equation for the alkene given to you assuming the reactant was Br2, in the presence of water indicating the stereochemistry of all products formed.
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Give the reaction equation for the
water indicating the stereochemistry of all products formed.
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- What two stereoisomeric alkanes are formed in the catalytic hydrogenation of (Z)-3-methyl-2-hexene? Draw and label the alkanes. In this reaction, what are the relative amounts of each of the two alkanes generated?The heat of hydrogenation of cis-2,2,5,5-tetramethyl-3-hexene is -154 kJ (-36.7 kcal)/ mol, while that of the trans isomer is only -113 kJ (-26.9 kcal)/mol. Q.) If a catalyst could be found that allowed equilibration of the cis and trans isomers at room temperature (such catalysts do exist), what would be the ratio of trans to cis isomers?Explain briefly and clearly the following concepts, taking as reference the molecule of n-butane and the corresponding drawings or illustrations. See pages 149-152 of the book Organic Chemistry, sixth edition (J. G. Smith). 4. What is steric hindrance in a conformation? Then draw a picture to illustrate the concept? 5. What is the torsional stress of a conformation? Then draw a picture to illustrate the concept? 6. Describe 1,3-diaxial interaction and illustrate with a specific example.
- Please give the organic product(s) for the following reaction. If no reaction occurs, explain why there is no reaction. You must indicate the correct stereochemistry.Is the conversion of 1-butene to 1,2-dibromobutane an oxidation, reduction or neither?Give the product for the addition of chlorine when HCl reacts with 3-Hexyne in acetic acid (CH3COOH). Show the correct stereochemistry, (is the product Z or E isomer).
- The same alkane is obtained from the catalytic hydrogenation of both alkene A and alkene B. The heat of hydrogenation of alkene A is 29.8 kcal/mol, and the heat of hydrogenation of alkene B is 31.4 kcal/mol. Which alkene is more stable?Reaction of H2 with ethylene, in the presence of a small amount of palladium catalyst, gives ethane (i) Assign oxidation states to all the atoms in the three substances in thisequation. (ii) Although there is no transfer of electrons in this reaction of organiccompounds, it is regarded as a redox reaction. Explain why this isreasonable, and specify which species is reduced and which is oxidised.What two stereoisomeric alkanes are formed from the catalytic hydrogenation of (z)-3-methyl-2-hexene? Draw and label the alkanes. What are the relative amounts of each alkane?
- Write the monobromination products of 1,4-dimethylcyclohexane and calculate the percentages of each product. Which is the major product?Draw the structure(s) of all of the alkene isomers, C5H10, that contain a branched chain. Consider E/Z stereochemistry of alkenes.Write the structure of the main products, reactants, starting materials, as applicable. The stereochemistry of reactants/products must be appropriate