H₂N 'OH H₂O* NH₂ NaOEt EtOH NH,CH, Sm NH₂ i ZI + H₂O remove

Organic Chemistry
9th Edition
ISBN:9781305080485
Author:John E. McMurry
Publisher:John E. McMurry
Chapter27: Biomolecules: Lipids
Section27.SE: Something Extra
Problem 47AP: Cembrene, C20H32, is a diterpenoid hydrocarbon isolated from pine resin. Cembrene has a UV...
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The following reactions will not produce the product given. Explain Briefly why. You may use pictures in your explanation.

Reaction:
دارند
H₂N
OH
CI
ia
CI
H₂O*
NH₂
NaOEt
EtOH
NH,CH3
&
NH₂
(CH3)2CuLi
LIAIH(t-BUO)3
Et₂O, -78°C
1) CH₂MgBr
2) H₂O*
OH
+ H₂O
remove
OH
+ EtOH
Explain with respect to nucleophilicity
Comment on the reactivity of the reagent. What product would
be produced?
Comment on the reactivity of the reagent. What product would
be produced?
Comment on the reactivity of the reagent. What product would
be produced?
Transcribed Image Text:Reaction: دارند H₂N OH CI ia CI H₂O* NH₂ NaOEt EtOH NH,CH3 & NH₂ (CH3)2CuLi LIAIH(t-BUO)3 Et₂O, -78°C 1) CH₂MgBr 2) H₂O* OH + H₂O remove OH + EtOH Explain with respect to nucleophilicity Comment on the reactivity of the reagent. What product would be produced? Comment on the reactivity of the reagent. What product would be produced? Comment on the reactivity of the reagent. What product would be produced?
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