HO H2SO4 (а) Н,С- heat `C,Hs (CH3)3COOH, OsO4(cat) (b) (CII3);COII, IIO- 1. B,H6, diglyme 2. Н-О, но (c) 1. LIAIH4, diethyl ether (d) 2. H-О OH H,CrO4 (e) CH3CHC=C(CH2);CH3 H2SO4, H20, acetone OH || (f) CH;ČCH,CH=CHCH,CCH3 1. LIAIH4, diethyl ether 2. H-о OH O,N || pyridine -CI (g) H3C O,N (h) + CH;COCCH3 -ОН H NO2 CH;OH (i) Cl H2SO4 НО NO2

Chemistry by OpenStax (2015-05-04)
1st Edition
ISBN:9781938168390
Author:Klaus Theopold, Richard H Langley, Paul Flowers, William R. Robinson, Mark Blaser
Publisher:Klaus Theopold, Richard H Langley, Paul Flowers, William R. Robinson, Mark Blaser
Chapter5: Thermochemistry
Section: Chapter Questions
Problem 52E: Before the introduction of chlorofluorocarbons, sulfur dioxide (enthalpy of vaporization, 6.00...
icon
Related questions
Question

Each of the following reactions has been reported in the chemical literature. Predict the product in each case, showing stereochemistry where appropriate.

HO
H2SO4
(а) Н,С-
heat
`C,Hs
(CH3)3COOH, OsO4(cat)
(b)
(CII3);COII, IIO-
1. B,H6, diglyme
2. Н-О, но
(c)
1. LIAIH4, diethyl ether
(d)
2. H-О
OH
H,CrO4
(e) CH3CHC=C(CH2);CH3
H2SO4, H20, acetone
OH
||
(f) CH;ČCH,CH=CHCH,CCH3
1. LIAIH4, diethyl ether
2. H-о
OH
O,N
||
pyridine
-CI
(g) H3C
O,N
(h)
+ CH;COCCH3
-ОН
H
NO2
CH;OH
(i)
Cl
H2SO4
НО
NO2
Transcribed Image Text:HO H2SO4 (а) Н,С- heat `C,Hs (CH3)3COOH, OsO4(cat) (b) (CII3);COII, IIO- 1. B,H6, diglyme 2. Н-О, но (c) 1. LIAIH4, diethyl ether (d) 2. H-О OH H,CrO4 (e) CH3CHC=C(CH2);CH3 H2SO4, H20, acetone OH || (f) CH;ČCH,CH=CHCH,CCH3 1. LIAIH4, diethyl ether 2. H-о OH O,N || pyridine -CI (g) H3C O,N (h) + CH;COCCH3 -ОН H NO2 CH;OH (i) Cl H2SO4 НО NO2
Expert Solution
trending now

Trending now

This is a popular solution!

steps

Step by step

Solved in 2 steps with 1 images

Blurred answer
Knowledge Booster
Selection Rules for Pericyclic Reactions
Learn more about
Need a deep-dive on the concept behind this application? Look no further. Learn more about this topic, chemistry and related others by exploring similar questions and additional content below.
Similar questions
  • SEE MORE QUESTIONS
Recommended textbooks for you
Chemistry by OpenStax (2015-05-04)
Chemistry by OpenStax (2015-05-04)
Chemistry
ISBN:
9781938168390
Author:
Klaus Theopold, Richard H Langley, Paul Flowers, William R. Robinson, Mark Blaser
Publisher:
OpenStax
Organic Chemistry
Organic Chemistry
Chemistry
ISBN:
9781305580350
Author:
William H. Brown, Brent L. Iverson, Eric Anslyn, Christopher S. Foote
Publisher:
Cengage Learning