How long will it take to dissolve 2 mg of metal A (atomic weight 100) in a solution containing A2+ from a metal electrode with area of 1.5 cm2 at an overpotential of = 0.2 V? The exchange current density (j0) for A is 3x10-3 A/cm2, the temperature T=298 K and the symmetry factor =0.4.

How long will it take to dissolve 2 mg of metal A (atomic weight 100) in a solution containing A2+ from a metal electrode with area of 1.5 cm2 at an overpotential of = 0.2 V? The exchange current density (j0) for A is 3x10-3 A/cm2, the temperature T=298 K and the symmetry factor =0.4.

Principles of Instrumental Analysis

7th Edition

ISBN:9781305577213

Author:Douglas A. Skoog, F. James Holler, Stanley R. Crouch

Publisher:Douglas A. Skoog, F. James Holler, Stanley R. Crouch

Chapter23: Potentiometry

Section: Chapter Questions

Problem 23.7QAP

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Concept explainers

Potentiometric Titrations

Potentiometric titration is one of the important titration methods and is mainly carried out to characterize acid solutions. It follows a method similar to that of the normal titration technique, but the main difference is that there is no indicator used in the potentiometric titrations. Instead of using an indicator, electrodes are employed for monitoring the whole titration process. A scientist named Robert Behrend did the potentiometric titration for the first time, and it was done using the mercurous solution and potassium chloride.

Question

How long will it take to dissolve 2 mg of metal A (atomic weight 100) in a solution

containing A2+ from a metal electrode with area of 1.5 cm2 at an overpotential of

= 0.2 V? The exchange current density (j0) for A is 3x10-3 A/cm2, the temperature

T=298 K and the symmetry factor =0.4.

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