Hydrogen iodide decomposes according to the reaction 2 HI(g) ⇌ H2(g) + I2(g) A sealed 1.50−L container initially holds 0.00623 mol of H2, 0.00414 mol of I2, and 0.0244 mol of HI at 703 K. When equilibrium is reached, the concentration of H2(g) is 0.00467 M. What are the concentrations of HI(g) and I2(g)? [I2]eq M [HI]eq

Chemistry: Principles and Practice
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Chapter14: Chemical Equilibrium
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Hydrogen iodide decomposes according to the reaction

2 HI(g) ⇌ H2(g) + I2(g)

A sealed 1.50−L container initially holds 0.00623 mol of H2, 0.00414 mol of I2, and 0.0244 mol of HI at 703 K. When equilibrium is reached, the concentration of H2(g) is 0.00467 M. What are the concentrations of HI(g) and I2(g)?

[I2]eq

M

[HI]eq

M

Expert Solution
Step 1

Given reaction

                      2 HI(g) ⇌ H2(g) + I2(g)

No. of moles   0.0244mol      0.00623mol   0.00414mol

Volume            1.5L                      1.5L                 1.5L

[initial]           0.016267M       0.004153M      0.00276 (mol/L)

Charge             -2x                        x                        x

Equilibrium     (0.016267-2x)  (x+ 0.004153)  (x+ 0.00276)

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