(i)Identify all the acidic hydrogens present in the following carbonyl compounds:(1) CH3-C-N(CH,)2 (2) CH3-C-CH,(3) CH,-O-C-CH,-C-O-CH, (4) CH,-ċ-OCH,(ii)Hence, rank the compounds (part (i) above) in the order of increasing or decreasingacidity by using the symbol “ <" or “>" in your answer.

Answered: Image /qna-images/answer/5809a5f2-3a8c-417d-9067-aeb5e8bf1387.jpg

(i) Identify all the acidic hydrogens present in the following carbonyl compounds: (1) CH,-C-N(CH,)2 (2) CH3-C-CH, (3) CH,-O-C-CH,-C-O-CH, (4) CH3-ċ-OCH, (ii) Hence, rank the compounds (part (i) above) in the order of increasing or decreasing acidity by using the symbol “ < " or “>" in your answer.

(i) Identify all the acidic hydrogens present in the following carbonyl compounds: (1) CH,-C-N(CH,)2 (2) CH3-C-CH, (3) CH,-O-C-CH,-C-O-CH, (4) CH3-ċ-OCH, (ii) Hence, rank the compounds (part (i) above) in the order of increasing or decreasing acidity by using the symbol “ < " or “>" in your answer.

Organic Chemistry

9th Edition

ISBN:9781305080485

Author:John E. McMurry

Publisher:John E. McMurry

Chapter20: Carboxylic Acids And Nitriles

Section20.SE: Something Extra

Problem 54AP

See similar textbooks

Similar questions

From 1 being the least acidic and 4 being the most acidic, arrange the following organic compounds in terms of increasing acidity
Which is the stronger base: N-methylaniline (C6H5NHCH3) or benzylamine (C6H5CH2NH2). Explain your reasoning, supporting it with appropriate resonance contributors.
Rank each of the following sets of nitrogen bases in terms of basicity and explain your answer
Rank the following acids in decreasing acidity. Explain your answer CH2ClCOOH, CHCl2COOH, CH3COOH
NO2 would stabilize an adjacent (-) charge through resonance, making it a –R substituent What is the more acidic proton in nitrocyclohexane? explain with proper resonance structures of the conjugate base.
Thiocyanic acid (HSCN) is an inorganic acid (pKa = 1.1 at 25 °C) that can be classified as “strong” largely due to resonance stabilization of its conjugate base, thiocyanate (SCN– ). In the space provided below, draw Lewis electron dot structures of SCN- and all of its important resonance forms.
NO2 being a deactivating group, increase the acidic nature of alcohol, by increasing the stability of the corresponding conjugate base. True False
Write the equilibrium-constant expressions and obtainnumerical values for each constant in. (a) the basic dissociation of aniline, C6H5NH2. (b) the acidic dissociation of hypochlorous acid,HClO. (c) the acidic dissociation of methyl ammoniumhydrochloride, CH3NH3Cl. (d) the basic dissociation of NaNO2. (e) the dissociation of H3AsO3to H3O+and AsO33-. (f) the reaction of C2O42-with H2O to give H2C2O4and OH-. show solution
Regarding to the following compounds: NH3, H2O, H2SA) Rank the following compounds in order of increasing acidityB) Mention their conjugate bases and rank according to increasing their basicity order
Rank the pKa values of acetic acid, ethanol, phenol, and explain the reason in detail
Rank and explain the following compounds in order of increasing acidity. ( indicate 1 more most reactive, 3 for least reactive, and 2 for the middle) a. Acetic acid, 2-chloro acetic acid, 2,2-dichloro acetic acid b. Benzoic acid, p-methylbenzoic acid, p-nitrobenzoic acid
How to approach this problem?