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I need help calculating these values make sure they are 3 sig fig!!!
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- If 0.3074 g of a mixture of pure KCl and KBr requires 30.98 mL of 0.1007 M AgNO3 solution for its titration, calculate the% KCl and KBr in the sample. (Pat Data: Cl, 35.453; Br, 79.904; K, 39.098)For complexometric titration of Ca (II) ions in the shell of an egg sample weighing 59,427 g, the necessary processes were applied to the egg shells and a sample of 100 mL was prepared. From the prepared sample, 1 mL was taken and diluted to 100 mL, the pH was adjusted, and two drops of EBT indicator were dripped on it. The prepared solution was titrated with 27.4 mL of EDTA solution set at 0.0097 M. Calculate the amount of calcium in the sample in CaCO3%. (Ca = 40g / mol, CaCO3= 100g / mol)A dried sample of commercial salt was prepared by a coning and quartering. A 0.911-g sample of the salt was dissolved and diluted to 250.0 mL in a volumetric flask. Repeat 10.00-mL aliquots of this solution were titrated with a 0.054 M silver nitrate solution, requiring 9.68 mL to reach equivalence. Calculate the %(w/w) NaCl in the original sample.
- A 110.00 mL solution of 0.00195 M A3B2 is added to a 160.00 mL solution of 0.00155 M C3D4. What is pQsp for A3D2?A 0.2386-g sample contained only NaCI and KBr. It was dissolved in water and required 48.40 mL of 0.04837M AgN03 for complete titration of both halides (giving AgCI(s) and AgBr(s)). Calculate the weight percent of Br in the solid sample.Calculate the molar solubility of Ag2S in a solution maintained at pH 11.00 and where the concentration of free ammonia is 0.100 M. Ag2S: pKsp = 48.70H2S: Ka1 = 1.0 x 10-7 ; Ka2 = 1.2 x 10-15[Ag(NH3)2]+: Kf1 = 2.04 x 103 ; Kf2 = 8.13 x 103
- 50 cm3 of 0.05 M weak acid solution is titrated with 0.1 M NaOH solution. The measured pH valuesare 7.345 and 7.497 at the consumptions of 6.0 and 6.1 cm3, respectively. What value of the buffer capacity can be calculated in the solution at pH = 7.421?If the molar solubility of Tl2S at 25 oC is 5.31e-08 mol/L, what is the Ksp at this temperature?Ksp = (b) It is found that 9.14e-08 g of Sc(OH)3 dissolves per 100 mL of aqueous solution at 25 oC. Calculate the solubility-product constant for Sc(OH)3.Ksp = (c) The Ksp of Cu3(PO4)2 at 25 oC is 1.40e-37. What is the molar solubility of Cu3(PO4)2?solubility = mol/LThe sulfur content of insoluble sulfides that do not readilydissolve in acid can be measured by oxidation with Br2to SO42.25Metal ions are then replaced with Hby an ion-exchange column,and sulfate is precipitated as BaSO4with a known excess ofBaCl2. The excess Ba2is then titrated with EDTA to determinehow much was present. (To make the indicator end point clearer,a small, known quantity of Zn2also is added. The EDTA titratesboth the Ba2and the Zn2.) Knowing the excess Ba2, we cancalculate how much sulfur was in the original material. To analyzethe mineral sphalerite (ZnS, FM 97.46), 5.89 mg of powderedsolid were suspended in a mixture of CCl4and H2O containing1.5 mmol Br2. After 1 h at 20 C and 2 h at 50 C, the powder dis-solved and the solvent and excess Br2were removed by heating.The residue was dissolved in 3 mL of water and passed throughan ion-exchange column to replace Zn2with H. Then 5.000 mLof 0.014 63 M BaCl2were added to precipitate all sulfate as BaSO4.After the addition of…