If the equivalency point for an acid titration is at a ph of 6.75 which indicator should you use to detect the end point for your titration? Select one: a. phenolphthalein, K₂=3.16x10-10 b. bromothymol blue, K₂= 5.00x108 c. thymol blue, K₁=1.9x102, K₂=6.3x10-10 d. Alizarin yellow, K₂= 1x10-11 e. methyl red, K₁= 1x10-5

If the equivalency point for an acid titration is at a ph of 6.75 which indicator should you use to detect the end point for your titration? Select one: a. phenolphthalein, K₂=3.16x10-10 b. bromothymol blue, K₂= 5.00x108 c. thymol blue, K₁=1.9x102, K₂=6.3x10-10 d. Alizarin yellow, K₂= 1x10-11 e. methyl red, K₁= 1x10-5

Chemistry

10th Edition

ISBN:9781305957404

Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste

Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste

Chapter15: Acid-base Equilibria

Section: Chapter Questions

Problem 18Q: Acidbase indicators mark the end point of titrations by magically turning a different color. Explain...

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a Draw a pH titration curve that represents the titration of 25.0 mL of 0.15 M propionic acid. CH3CH2COOH, by the addition of 0.15 M KOH from a buret. Label the axes and put a scale on each axis. Show where the equivalence point and the buffer region are on the titration curve. You should do calculations for the 0%, 50%, 60%, and 100% titration points. b Is the solution neutral, acidic, or basic at the equivalence point? Why?
a Draw a pH titration curve that represents the titration of 50.0 mL of 0.10 M NH3 by the addition of 0.10 M HCl from a buret. Label the axes and put a scale on each axis. Show where the equivalence point and the buffer region are on the titration curve. You should do calculations for the 0%, 30%, 50%, and 100% titration points. b Is the solution neutral, acidic, or basic at the equivalence point? Why?
Acidbase indicators mark the end point of titrations by magically turning a different color. Explain the magic behind acidbase indicators.
Draw the general titration curve for a strong acid titrated by a strong base. At the various points in the titration, list the major species present before any reaction takes place and the major species present after any reaction takes place. What reaction takes place in a strong acidstrong base titration? How do you calculate the pH at the various points along the curve? What is the pH at the equivalence point for a strong acidstrong base titration? Why?
A buffer is composed of formic acid and its conjugate base, the formate ion. (a) What is the pH of a solution that has a formic acid concentration of 0.050 M and a sodium formate concentration of 0.035 M? (b) What must the ratio of acid to conjugate base be to have a pH value 0.50 units higher than the value calculated in part (a)?
The titration curves for two acids with the same base are shown on this graph. (a) Which is the curve for the weaker acid? Explain your choice. (b) Give the approximate pH at the equivalence point for the titration of each acid. (c) Explain why the pH at the equivalence point differs for each acid. (d) Explain why the starting pH values of the two acids differ. (e) Which indicator or indicators, phenolphthalein, bromthymol blue, or methyl red, could be used for the titration of Acid 1? For the titration of Acid 2? Explain your choices.
For the titration of 50.0 mL of 0.100-M HCl with 0.100-M NaOH, calculate the pH when these volumes of NaOH have been added: (a) 10.0 mL (b) 25.00 mL (c) 45.0 mL (d) 50.5 mL
Aniline hydrochloride, (C6H5NH3)Cl, is a weak acid. (Its conjugate base is the weak base aniline, C6H5NH2.) The acid can be titrated with a strong base such as NaOH. C6H5NH3+(aq)+OH(aq)C6H5NH2(aq)+H2O(l) Assume 50.0 mL of 0.100 M aniline hydrochloride is titrated with 0.185 M NaOH. (Ka for aniline hydrochloride is 2.4 105.) (a) What is the pH of the (C6H5NH3) solution before the titration begins? (b) What is the pH at the equivalence point? (c) What is the pH at the halfway point of the titration? (d) Which indicator in Figure 17.11 could be used to detect the equivalence point? (e) Calculate the pH of the solution after adding 10.0, 20.0, and 30.0 mL of base. (f) Combine the information in parts (a), (b), (c), and (e), and plot an approximate titration curve.
When 40.00 mL of a weak monoprotic acid solution is titrated with 0.100-M NaOH, the equivalence point is reached when 35.00 mL base has been added. After 20.00 mL NaOH solution has been added, the titration mixture has a pH of 5.75. Calculate the ionization constant of the acid.