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- Acid-catalyzed dehydration of neopentyl alcohol, (CH3)3CCH2OH, yields 2-methyl-2- butene as the major product. Outline a mechanism showing all steps in its formation.(ii) The elimination reaction between 2-bromobutane and NaOCH2CH3 gives two organic products. Draw a mechanism for the reaction which produces the major organic elimination product and provide a rationale as to why that is the major product.Explain and detail the reaction mechanism: NaBr + H2O + n-butyl alcohol = ?
- For the base-catalysed hydrolysis of 3-bromo-3-methylhexane (i.e. reaction with the nucleophile OH-): For the reaction intermediate, draw its structure and give the VSEPR description of the geometry at the reaction centre Give the names and draw the structures of the two reaction products. Explain your conclusions.(ii) The elimination reaction between 2-bromobutane and NaOCH2CH3 gives two organic products. Draw a mechanism for the reaction which produces the major organic elimination product and provide a rationale as to why that is the major product.(with explanation)Draw the reaction mechanism of conversion of compound 4a to 4b. Indicate what type of reaction mechanism. Write conditions and reagents used if there are any. Provide brief background in every step of the reaction mechanism.
- A) Provide the reagent and reaction mechanism to show how the reactants and products in the following reaction can interconvert B) under what conditions would the reaction I) favour reactants, II) favour the products and III) why?(i) Name, draw and describe the organic product of the reaction between 2-methylbut-1-ene and H2O in the presence of H2SO4 and provide a clear rationale as to why this is the major product of the reaction. (ii) The elimination reaction between 2-bromobutane and NaOCH2CH3 gives two organic products. Draw a mechanism for the reaction which produces the major organic elimination product and provide a rationale as to why that is the major product.The rate law for addition of Br2 to an alkene is first orderin Br2 and first order in the alkene. Does this informationsuggest that the mechanism of addition of Br2 to analkene proceeds in the same manner as for addition of HBr?Explain.
- One possible way of determining the identity of an alkene, is to let itundergo an oxidative cleavage reaction in the presence of hot basicpotassium permanganate. You are given two containers said to containdifferent alkenes. Container A is marked as cis / trans‐2‐butene andcontainer B as 2‐methyl‐1‐butene. Explain by referring to the formation ofproducts, how you would verify the identity of the alkenes.When A is reacted with hot aqueous NaOH, a compound B of molecular formula C8H11NO is produced. With this information, write the correct structure of B and propose the reaction mechanism (step by step, with the correct use of arrows) to obtain B.In the reactions given below, write to which organic molecule Y, Z, T, A ‘belongs, and give information about the reaction types that take place.
