In a heating curve, heat is (usually) added at a constant rate. Again using the methanol heating curve, a longer horizontal region at 64°C (versus –97.7°C) indicates that: (See attached image) solid methanol os the most stable form the heat of fusion is greater than the heat of vaporization more energy is needed to vaporize methanol gaseous methanol is the most stable form

Principles of Instrumental Analysis
7th Edition
ISBN:9781305577213
Author:Douglas A. Skoog, F. James Holler, Stanley R. Crouch
Publisher:Douglas A. Skoog, F. James Holler, Stanley R. Crouch
Chapter31: Thermal Methods
Section: Chapter Questions
Problem 31.3QAP
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In a heating curve, heat is (usually) added at a constant rate. Again using the methanol heating curve, a longer horizontal region at 64°C (versus –97.7°C) indicates that: (See attached image)

solid methanol os the most stable form
the heat of fusion is greater than the heat of vaporization
more energy is needed to vaporize methanol
gaseous methanol is the most stable form
120
90
BP= 64°C
30
-30
-60
MP = -97.7°C
-120
Energy Added
Temperature (°C)
Transcribed Image Text:120 90 BP= 64°C 30 -30 -60 MP = -97.7°C -120 Energy Added Temperature (°C)
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