In the laboratory a student burns a 0.366-g sample of 1,8-octanediol (C3H18O2) in a bomb calorimeter containing 1060. g of water. The temperature increases from 24.80 °C to 27.20 °C. The heat capacity of water is 4.184 J gloC The molar heat of combustion is -5094 kJ per mole of 1,8-octanediol. C3H1802(s) + 23/2 02(g) 8 C02(g) - 9 H,0(1) + Energy Calculate the heat capacity of the calorimeter.

Introduction to Chemical Engineering Thermodynamics
8th Edition
ISBN:9781259696527
Author:J.M. Smith Termodinamica en ingenieria quimica, Hendrick C Van Ness, Michael Abbott, Mark Swihart
Publisher:J.M. Smith Termodinamica en ingenieria quimica, Hendrick C Van Ness, Michael Abbott, Mark Swihart
Chapter1: Introduction
Section: Chapter Questions
Problem 1.1P
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Ignition
wires
heat
Thermometer
Stirrer
A bomb calorimeter, or constant volume calorimeter, is a device often used to
determine the heat of combustion of fuels and the energy content of foods.
sample
Since the "bomb" itself can absorb energy, a separate experiment is needed to
determine the heat capacity of the calorimeter. This is known as calibrating the
calorimeter.
Water
In the laboratory a student burns a 0.366-g sample of 1,8-octanediol (C3H18O2) in a
bomb calorimeter containing 1060. g of water. The temperature increases from 24.80
°C to 27.20 °C. The heat capacity of water is 4.184 J gloC-!
The molar heat of combustion is -5094 kJ per mole of 1,8-octanediol.
C3H18O2(s) + 23/2 O2(g) 8 CO2(g) + 9 H,0(1) + Energy
Calculate the heat capacity of the calorimeter.
Insulated
outside
chamber
Sample
dish
Burning
sample
Steel
bomb
heat capacity of calorimeter =
J/°C
Combustion (bomb) calorimeter.
Transcribed Image Text:Ignition wires heat Thermometer Stirrer A bomb calorimeter, or constant volume calorimeter, is a device often used to determine the heat of combustion of fuels and the energy content of foods. sample Since the "bomb" itself can absorb energy, a separate experiment is needed to determine the heat capacity of the calorimeter. This is known as calibrating the calorimeter. Water In the laboratory a student burns a 0.366-g sample of 1,8-octanediol (C3H18O2) in a bomb calorimeter containing 1060. g of water. The temperature increases from 24.80 °C to 27.20 °C. The heat capacity of water is 4.184 J gloC-! The molar heat of combustion is -5094 kJ per mole of 1,8-octanediol. C3H18O2(s) + 23/2 O2(g) 8 CO2(g) + 9 H,0(1) + Energy Calculate the heat capacity of the calorimeter. Insulated outside chamber Sample dish Burning sample Steel bomb heat capacity of calorimeter = J/°C Combustion (bomb) calorimeter.
Ignition
wires
heat
Thermometer
Stirrer
A bomb calorimeter, or a constant volume calorimeter, is a device often used to
determine the heat of combustion of fuels and the energy content of foods.
sample
In an experiment, a 0.8006 g sample of phthalic acid (C3H,04) is burned
completely in a bomb calorimeter. The calorimeter is surrounded by 1.112×10° g of
water. During the combustion the temperature increases from 23.08 to 25.98 °C. The
heat capacity of water is 4.184 J gl°C•!
Water
The heat capacity of the calorimeter was determined in a previous experiment to be
891.8 J/°C.
Assuming that no energy is lost to the surroundings, calculate the molar heat of
combustion of phthalic acid based on these data.
C3H,O4(s) – (15/2) O2(g) →3 H2O(1) = 8 CO>(g) + Energy
Insulated
outside
chamber
Sample
dish
Burning
sample
Steel
bomb
Molar Heat of Combustion =
kJ/mol
Combustion (bomb) calorimeter.
Transcribed Image Text:Ignition wires heat Thermometer Stirrer A bomb calorimeter, or a constant volume calorimeter, is a device often used to determine the heat of combustion of fuels and the energy content of foods. sample In an experiment, a 0.8006 g sample of phthalic acid (C3H,04) is burned completely in a bomb calorimeter. The calorimeter is surrounded by 1.112×10° g of water. During the combustion the temperature increases from 23.08 to 25.98 °C. The heat capacity of water is 4.184 J gl°C•! Water The heat capacity of the calorimeter was determined in a previous experiment to be 891.8 J/°C. Assuming that no energy is lost to the surroundings, calculate the molar heat of combustion of phthalic acid based on these data. C3H,O4(s) – (15/2) O2(g) →3 H2O(1) = 8 CO>(g) + Energy Insulated outside chamber Sample dish Burning sample Steel bomb Molar Heat of Combustion = kJ/mol Combustion (bomb) calorimeter.
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