(iv) When A was converted with hot potassium permanganate to form C, followed by esterification with ethanol, a di-ester D .was formed: What is the structure of C and D. KMNO4, -OH 2 OH C H;O+, heat H2SO4
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- Propose a mechanism for the acid-catalyzed hydration of propene. Remember that a mechanism must include curved arrows to show movement of electrons, as well as all intermediates.(i) Name, draw and describe the organic product of the reaction between 2-methylbut-1-ene and H2O in the presence of H2SO4 and provide a clear rationale as to why this is the major product of the reaction. (ii) The elimination reaction between 2-bromobutane and NaOCH2CH3 gives two organic products. Draw a mechanism for the reaction which produces the major organic elimination product and provide a rationale as to why that is the major product.In which of the statements given below, the event is not an oxidation reaction? A. Reaction of an alkyl halide with ammonia B. Formation of the product as a result of the reaction of 2-propene at KMnO4 / Basic ambient temperature C. Formation of the product as a result of the reaction of 2-propene in KMnO4 / Basic medium cold D. Formation of the product as a result of the reaction of benzoine with nitric acid E. CH3CH2OH + KMnO4 ® CH3COOH
- write the reaction of the action of methyl-2, bromo-2-propane with hot KOH solution. a) Name the formed product b) Explain why the reaction takes place according to the SNI mechanismWhen the hypochlorite oxidation is performed on secondary alcohols such as 1-phenolethanol, the product of the reaction is benzoate ion and trichloromethane if an excess of hypochlorite is used in the absence of a buffer to keep the pH below 10. Explain the formation of these products (Hint: what reaction do the products remind you of?) Provide a complete mechanism?consider the route to the Tafenoquine with respect to green chemistry priniciples what are the two instances of reaction conditions which are potentially unsuitable for further process development?
- Explain and detail the reaction mechanism: NaBr + H2O + n-butyl alcohol = ?The mechanism of the Fischer esterification was controversial until 1938, when IrvingRoberts and Harold Urey of Columbia University used isotopic labeling to follow thealcohol oxygen atom through the reaction. A catalytic amount of sulfuric acid was addedto a mixture of 1 mole of acetic acid and 1 mole of special methanol containing the heavy18O isotope of oxygen. After a short period, the acid was neutralized to stop the reaction,and the components of the mixture were separated.H2SO4OCH3 C O H CH3 O H CH3 C O CH3 H2OO18 + +(a) Propose a mechanism for this reaction.(b) Follow the labeled 18O atom through your mechanism, and show where it is found inthe products.(c) The 18O isotope is not radioactive. Suggest how you could experimentally determinethe amounts of 18O in the separated components of the mixtureChemistry Please answer the following two questions. 1.) Why are functional group interconversions controversial? (double bonds into epoxide) 2.) Explain the clincal trials that happen for epoxide containing molecules
- a)Step by step show the reaction of 1 mol of water from the 3,3-dimethyl-2-pentanol compound in acid-catalyzed medium.Name the main product formed. b)Indicate whether the resulting product shows the geometric isomer or not. c)Write the products formed when the product is ozonized and oxidized.(ii) The elimination reaction between 2-bromobutane and NaOCH2CH3 gives two organic products. Draw a mechanism for the reaction which produces the major organic elimination product and provide a rationale as to why that is the major product.The reaction of sodium borohydride with ketones proceeds rapidly at room temperature, forming an intermediate borate ester which is hydrolyzed to give the product alcohol: 4 R2C=O + Na+BH4- ---> (R2CHO)4B-Na+ (R2CHO)4B-Na+ + 2H2O ---> 4R2CHOH + Na+BO2- Rewrite these two steps using benzil as the ketone, and using structural formulas throughout, rather than the condensed forms above.