Can you help me break down the fragmentation of this mass spec spectra? Although the compound is not given, using the H NMR, C NMR and IR spectras that were also given, I found the compound to be CH3-COOH-CH2-CH2-CH2-CH3 (butyl acetate) In this Mass spec, it is given that M+=116 and I have found that fragmenting CH3 is 101, then CH2 is 87, and CH2 again is 73. I am just lost on where to go from there, while being left with CH3-COOH-CH2, because there are multiple peaks between 43 and 73 that I can't seem to figure out. Any help would be great!

Principles of Instrumental Analysis
7th Edition
ISBN:9781305577213
Author:Douglas A. Skoog, F. James Holler, Stanley R. Crouch
Publisher:Douglas A. Skoog, F. James Holler, Stanley R. Crouch
Chapter32: Radiochemical Methods
Section: Chapter Questions
Problem 32.13QAP
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Can you help me break down the fragmentation of this mass spec spectra? Although the compound is not given, using the H NMR, C NMR and IR spectras that were also given, I found the compound to be CH3-COOH-CH2-CH2-CH2-CH3 (butyl acetate)

In this Mass spec, it is given that M+=116 and I have found that fragmenting CH3 is 101, then CH2 is 87, and CH2 again is 73. I am just lost on where to go from there, while being left with CH3-COOH-CH2, because there are multiple peaks between 43 and 73 that I can't seem to figure out.

Any help would be great! 

Relative Intensity
100
80
Ö
O
20
миниито
10
M+= 116
20
30 40
50
60
m/z
70
powqurubluqunuqtangguptag
100 110 120
80
90
Transcribed Image Text:Relative Intensity 100 80 Ö O 20 миниито 10 M+= 116 20 30 40 50 60 m/z 70 powqurubluqunuqtangguptag 100 110 120 80 90
H
H—C-C
Η
Η Η Η Η
-C-C-C-C-H
Η Η Η Η
Butyl Acetate
Transcribed Image Text:H H—C-C Η Η Η Η Η -C-C-C-C-H Η Η Η Η Butyl Acetate
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