Look at the imide, the nitrogen analog of an anhydride below: a) For a neutral imide, will the carbonyl carbon be more (easier to attack) or less (harder to attack) electrophilic than the C of a neutral anhydride? Talk about electronegativties of Nitrogen (imide) vs Oxygen (anyhydride) b) If the imide is hydrolyzed under acidic conditions, which atom, one of the oxygens or the nitrogen, will be protonated? Explain your answer. Talk about pka and keq.

Appl Of Ms Excel In Analytical Chemistry
2nd Edition
ISBN:9781285686691
Author:Crouch
Publisher:Crouch
Chapter2: Basic Statistical Analysis With Excel
Section: Chapter Questions
Problem 12P
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Look at the imide, the nitrogen analog of an anhydride below:

a) For a neutral imide, will the carbonyl carbon be more (easier to attack) or
less (harder to attack) electrophilic than the C of a neutral anhydride? Talk about electronegativties of Nitrogen (imide) vs Oxygen (anyhydride)


b) If the imide is hydrolyzed under acidic conditions, which atom, one of the
oxygens or the nitrogen, will be protonated? Explain your answer. Talk about pka and keq.

PIN:
-
.O.
O.:
=0
Transcribed Image Text:PIN: - .O. O.: =0
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shouldn't part b be oxygen due to resonance and stability?

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