Methanoic acid, HCOOH(aq) , is a monoprotic acid that can be synthesized by the reaction between CO and NH3 in the presence of hydronium ions. A proposed mechanism for the reaction consists of the three elementary steps shown below. Step 1: CH3 OH + CO → HCO2CH3 slow Step 2: HCO2CH3 + NH3 → HCONH2 + CH3 OH fast Step 3: HCONH2 + H3 O+ → HCOOH + NH4 + fast Overall reaction: CO + NH3 + H3 O+ → HCOOH + NH4 + ΔHrxn = −81 kJ/molrxn
Methanoic acid, HCOOH(aq) , is a monoprotic acid that can be synthesized by the reaction between CO and NH3 in the presence of hydronium ions. A proposed mechanism for the reaction consists of the three elementary steps shown below. Step 1: CH3 OH + CO → HCO2CH3 slow Step 2: HCO2CH3 + NH3 → HCONH2 + CH3 OH fast Step 3: HCONH2 + H3 O+ → HCOOH + NH4 + fast Overall reaction: CO + NH3 + H3 O+ → HCOOH + NH4 + ΔHrxn = −81 kJ/molrxn
Chemistry by OpenStax (2015-05-04)
1st Edition
ISBN:9781938168390
Author:Klaus Theopold, Richard H Langley, Paul Flowers, William R. Robinson, Mark Blaser
Publisher:Klaus Theopold, Richard H Langley, Paul Flowers, William R. Robinson, Mark Blaser
Chapter5: Thermochemistry
Section: Chapter Questions
Problem 2E: Prepare a table identifying several energy transitions that take place during the typical operation...
Related questions
Question
Methanoic acid, HCOOH(aq) , is a monoprotic acid that can be synthesized by the reaction between CO and NH3 in the presence of hydronium ions. A proposed mechanism for the reaction consists of the three elementary steps shown below.
Step 1: CH3 OH + CO → HCO2CH3 slow
Step 2: HCO2CH3 + NH3 → HCONH2 + CH3 OH fast Step 3: HCONH2 + H3 O+ → HCOOH + NH4 + fast Overall reaction: CO + NH3 + H3 O+ → HCOOH + NH4 + ΔHrxn = −81 kJ/molrxn
Expert Solution
This question has been solved!
Explore an expertly crafted, step-by-step solution for a thorough understanding of key concepts.
This is a popular solution!
Trending now
This is a popular solution!
Step by step
Solved in 2 steps
Knowledge Booster
Learn more about
Need a deep-dive on the concept behind this application? Look no further. Learn more about this topic, chemistry and related others by exploring similar questions and additional content below.Recommended textbooks for you
Chemistry by OpenStax (2015-05-04)
Chemistry
ISBN:
9781938168390
Author:
Klaus Theopold, Richard H Langley, Paul Flowers, William R. Robinson, Mark Blaser
Publisher:
OpenStax
General Chemistry - Standalone book (MindTap Cour…
Chemistry
ISBN:
9781305580343
Author:
Steven D. Gammon, Ebbing, Darrell Ebbing, Steven D., Darrell; Gammon, Darrell Ebbing; Steven D. Gammon, Darrell D.; Gammon, Ebbing; Steven D. Gammon; Darrell
Publisher:
Cengage Learning
Introduction to General, Organic and Biochemistry
Chemistry
ISBN:
9781285869759
Author:
Frederick A. Bettelheim, William H. Brown, Mary K. Campbell, Shawn O. Farrell, Omar Torres
Publisher:
Cengage Learning
Chemistry by OpenStax (2015-05-04)
Chemistry
ISBN:
9781938168390
Author:
Klaus Theopold, Richard H Langley, Paul Flowers, William R. Robinson, Mark Blaser
Publisher:
OpenStax
General Chemistry - Standalone book (MindTap Cour…
Chemistry
ISBN:
9781305580343
Author:
Steven D. Gammon, Ebbing, Darrell Ebbing, Steven D., Darrell; Gammon, Darrell Ebbing; Steven D. Gammon, Darrell D.; Gammon, Ebbing; Steven D. Gammon; Darrell
Publisher:
Cengage Learning
Introduction to General, Organic and Biochemistry
Chemistry
ISBN:
9781285869759
Author:
Frederick A. Bettelheim, William H. Brown, Mary K. Campbell, Shawn O. Farrell, Omar Torres
Publisher:
Cengage Learning
Chemistry for Engineering Students
Chemistry
ISBN:
9781337398909
Author:
Lawrence S. Brown, Tom Holme
Publisher:
Cengage Learning
Living By Chemistry: First Edition Textbook
Chemistry
ISBN:
9781559539418
Author:
Angelica Stacy
Publisher:
MAC HIGHER