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Fill in the boxes below with the appropriate reagents or structures. Each part includes a hydrolysis reaction, thus the boxes should contain two products (assume that the pH has been adjusted so that the products exist as neutrally charged species).
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- Isoleucine, another of the twenty amino acids found in proteins, is metabolized by a pathway that includes the following step. Propose a mechanism.What reagents are needed to convert (CH3CH2)3CC=CH to each compound?Draw the products formed (including stereoisomers) when each compound is reduced with NaBH4 in CH3OH.
- Which of these reagent(s) will not react with HOCH2CH2CH2COOH? A) NaCN in ethanol B) C2H5OH in the presence of an acid catalyst. C) (CH3CO)2O D) Concentrated H2SO4Draw the products formed when CH3COCH2CH2CH = CH2 is treated with each reagent:(a) LiAlH4, then H2O;(b) NaBH4 in CH3OH;(c) H2 (1 equiv), Pd-C;(d) H2 (excess), Pd-C;(e) NaBH4 (excess) in CH3OH;(f) NaBD4 in CH3OH.Which substance in each pair should have the greater ∆Hvap? CH3CH2CH2CH2CH3 or CH3CH2CH2CH2CH2OH CH3–O–CH3 or CH3CH2OH