Nitrogen content of an organic compound can be determined by the Dumas Method. The compound is passed over hot copper (II) oxide and reacts as follows: Compound N 2 + CO 2 + H 20The product gases are passed through a solution of potassium hydroxide to remove CO2. The remaining gas is N2 saturated with H20 vapour. In a given experiment 0.225g of the unknown compound produces 27.8mL of N2 saturated with H2O vapor at 25oC and 730Torr. What mass is the % of nitrogen in the compound? (NB: vapour pressure of H2O at this temperature is 23.8Torr.)

Chemistry: Principles and Practice
3rd Edition
ISBN:9780534420123
Author:Daniel L. Reger, Scott R. Goode, David W. Ball, Edward Mercer
Publisher:Daniel L. Reger, Scott R. Goode, David W. Ball, Edward Mercer
Chapter11: Liquids And Solids
Section: Chapter Questions
Problem 11.1QE
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Nitrogen content of an organic compound can be determined by the Dumas Method.
The compound is passed over hot copper (II) oxide and reacts as follows: Compound N 2 + CO 2 + H 20
The product gases are passed through a solution of potassium hydroxide to remove CO2.
The remaining gas is N2 saturated with H20 vapour. In a given experiment 0.225g of the unknown compound produces 27.8mL of N2 saturated with H2O vapor at 25oC and
730Torr. What mass is the % of nitrogen in the compound? (NB: vapour pressure of H2O
at this temperature is 23.8Torr.)

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