2. In the following reaction, N0, is a brown gas and N,0, is colorless.NO2 (g) = 2 N,04 (g)(colorless)(brown)a. When the temperature decreases, the color of the equilibrium mixture gets lighter. Is thisreaction exothermic or endothermic?b. What will happen to the value of the equilibrium constant, K, if the temperature of thereaction is increased?

As by decreasing temperature equilibrium moves forward direction hehce, Reaction is exothermic 2)…

NO2 (g) = 2 N204 (g) (brown) (colorless) When the temperature decreases, the color of the equilibrium mixture gets lighter. Is reaction exothermic or endothermic? What will happen to the value of the equilibrium constant, K, if the temperature of th reaction is increased?

NO2 (g) = 2 N204 (g) (brown) (colorless) When the temperature decreases, the color of the equilibrium mixture gets lighter. Is reaction exothermic or endothermic? What will happen to the value of the equilibrium constant, K, if the temperature of th reaction is increased?

Chemistry: An Atoms First Approach

2nd Edition

ISBN:9781305079243

Author:Steven S. Zumdahl, Susan A. Zumdahl

Publisher:Steven S. Zumdahl, Susan A. Zumdahl

Chapter12: Chemical Equilibrium

Section: Chapter Questions

Problem 45E: A 1.00-L flask was filled with 2.00 moles of gaseous SO2 and 2.00 moles of gaseous NO2 and heated....

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What is Le Chteliers principle? Consider the reaction 2NOCI(g)2NO(g)+Cl2(g) If this reaction is at equilibrium. what happens when the following changes occur? a. NOCI(g) is added. b. NO(g) is added. c. NOCI(g) is removed. d. Cl2(g) is removed. e. The container volume is decreased. For each of these changes, what happens to the value of K for the reaction as equilibrium is reached again? Give an example of a reaction for which the addition or removal of one of the reactants or products has no effect on the equilibrium position. In general, how will the equilibrium position of a gas-phase reaction be affected if the volume of the reaction vessel changes? Are there reactions that will not have their equilibria shifted by a change in volume? Explain. Why does changing the pressure in a rigid container by adding an inert gas not shift the equilibrium position for a gas-phase reaction?
Hydrogen and carbon dioxide react at a high temperature to give water and carbon monoxide. H2(g) + CO2(g) H2O(g) + CO(g) (a) Laboratory measurements at 986 C show that there are 0.11 mol each of CO and H2O vapor and 0.087 mol each of H2 and CO2 at equilibrium in a 50.0-L container. Calculate the equilibrium constant for the reaction at 986 C. (b) Suppose 0.010 mol each of H2 and CO2 are placed in a 200.0-L container. When equilibrium is achieved at 986 C, what amounts of CO(g) and H2O(g), in moles, would be present? [Use the value of Kc from part (a).]
Consider the reaction 2N2O(g) + O2(g) 4NO(g) Suppose the system is at equilibrium, and then an additional mole of N2O(g) is injected into the system at constant temperature. Once the reaction reestablishes equilibrium, has the amount of N2O increased or decreased from its original equilibrium amount? Explain. What happens to the value of the equilibrium constant with this change?
Consider the system 4 NH3(g) + 3 O2(g) ⇌ 2 N2(g) + 6 H20(ℓ) ΔrH° = −1530.4 kJ/mol How will the amount of ammonia at equilibrium be affected by removing O2(g) without changing the total gas volume? adding N2(g) without changing the total gas volume? adding water without changing the total gas volume? expanding the container? increasing the temperature? Which of these changes (i to v) increases the value of K? Which decreases it?
At room temperature, the equilibrium constant Kc for the reaction 2 NO(g) ⇌ N2(g) + O2(g) is 1.4 × 1030. Is this reaction product-favored or reactant-favored? Explain your answer. In the atmosphere at room temperature the concentration of N2 is 0.33 mol/L, and the concentration of O2 is about 25% of that value. Calculate the equilibrium concentration of NO in the atmosphere produced by the reaction of N2 and O2. How does this affect your answer to Question 11?
The creation of shells by mollusk species is a fascinating process. By utilizing the Ca2+ in their food and aqueous environment, as well as some complex equilibrium processes, a hard calcium carbonate shell can be produced. One important equilibrium reaction in this complex process is HCO3(aq)H+(aq)+CO32(aq)K=5.61011 If 0.16 mole of HCO3 is placed into 1.00 L of solution, what will be the equilibrium concentration of CO32?
At 2300 K the equilibrium constant for the formation of NO(g) is 1.7 103. N2(g) + O2(g) 2 NO(g) (a) Analysis shows that the concentrations of N2 and O2 are both 0.25 M, and that of NO is 0.0042 M under certain conditions. Is the system at equilibrium? (b) If the system is not at equilibrium, in which direction does the reaction proceed? (c) When the system is at equilibrium, what are the equilibrium concentrations?
12.103 Methanol, CH3OH, can be produced by the reaction of CO with H2, with the liberation of heat. All species in the reaction are gaseous. What effect will each of the following have on the equilibrium concentration of CO? (a) Pressure is increased, (b) volume of the reaction container is decreased, (c) heat is added, (d) the concentration of CO is increased, (e) some methanol is removed from the container, and (f) H2 is added.
The decomposition of NH4HS, NH 4 HS( s )NH3( g )+ H 2 S( g ) is an endothermic process. Using Le Chatelier's principle, explain how increasing the temperature would affect the equilibrium. If more NH4HS is added to a flask in which this equilibrium exists, how is the equilibrium affected? What if some additional NH3 is placed in the flask? What will happen to the pressure of NH3 if some H2S is removed from the flask?
Solid NH4HS decomposes by the following endothermic process: NH4HS(s) NH3(g) + H2S(g) a. What effect will adding more NH3(g) have on the equilibrium? b. What effect will adding more NH4HS(s) have on the equilibrium? c. What effect will increasing the volume of the container have on the equilibrium? d. What effect will decreasing the temperature have on the equilibrium?
Consider the following equilibrium: COBr2(g) CO(g) + Br2(g)Kc = 0.190 at 73 C (a) A 0.50 mol sample of COBr2 is transferred to a 9.50-L flask and heated until equilibrium is attained. Calculate the equilibrium concentrations of each species. (b) The volume of the container is decreased to 4.5 L and the system allowed to return to equilibrium. Calculate the new equilibrium concentrations. (Hint: The calculation will be easier if you view this as a new problem with 0.5 mol of COBr2 transferred to a 4.5-L flask.) (c) What is the effect of decreasing the container volume from 9.50 L to 4.50 L?
Because calcium carbonate is a sink for CO32- in a lake, the student in Exercise 12.39 decides to go a step further and examine the equilibrium between carbonate ion and CaCOj. The reaction is Ca2+(aq) + COj2_(aq) ** CaCO,(s) The equilibrium constant for this reaction is 2.1 X 10*. If the initial calcium ion concentration is 0.02 AI and the carbonate concentration is 0.03 AI, what are the equilibrium concentrations of the ions? A student is simulating the carbonic acid—hydrogen carbonate equilibrium in a lake: H2COj(aq) H+(aq) + HCO}‘(aq) K = 4.4 X 10"7 She starts with 0.1000 AI carbonic acid. What are the concentrations of all species at equilibrium?