он D From the structures above, select the compound(s) with the following properties: a) The compound which would NOT yield 2-propanone when treated with H20/H3O*: b) The compound which would yield 2-propanone when treated with H2O/OH: c) The compound prepared from acetone, 1,2-ethanediol, and an acid catalyst:
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- Ibufenac, a para-disubstituted arene with the structure HO2CCH26H4CH2CH(CH3)2, is a much more potent analgesic than aspirin, but it was never sold commercially because it caused liver toxicity in some clinical trials. Devise a synthesis of ibufenac from benzene and organic halides having fewer than five carbons.Ibufenac, a para-disubstituted arene with the structureHO2CCH2C6H4CH2CH(CH3)2 , is a much more potent analgesic thanaspirin, but it was never sold commercially because it caused livertoxicity in some clinical trials. Devise a synthesis of ibufenac frombenzene and organic halides having fewer than five carbons.Devise a synthesis of (E)-tetradec-11-enal, a sex pheromone of thespruce budworm, a pest that destroys fir and spruce forests, fromacetylene, Br(CH2)10OH, and any needed organic compounds orinorganic reagents.
- what ate the structures for the following cinnamate reacts with methyl cinnamate reacts with ethyl cinnamate reacts with 1-propyl cinnamate reacts with 2-propylDraw the product formed when phenylacetic acid (C6H5CH2COOH) istreated with following reagent. With some reagents, no reaction occurs. CH3NH2, DCCEleostearic acid, C18H30O2, is a rare fatty acid found in the tung oil used for finishing furniture. On ozonolysis followed by treatment with zinc, eleostearic acid furnishes one part pentanal, two parts glyoxal (OHC-CHO), and one part 9-oxononanoic acid [OHC(CH2)7CO2H]. What is the structure of eleostearic acid?
- The key step in a reported laboratory synthesis of sativene, a hydrocarbon isolated from the mold Helminthosporium sativum, involves the following base treatment of a keto tosylate. What kind of reaction is occurring? How would you complete the synthesis?Which of the following reaction or reagent does not produce an amine molecule? A. Curtius rearrangementB. Reaction of oximes with metallic sodium in ethanolC. Reaction of N-alkylphthalimide with hydrazineD. Hofmann transformationE. Wolff transformationDevise a synthesis of (E)-tetradec-11-enal, a sex pheromone of the spruce budworm, a pest that destroys r and spruce forests, from acetylene, Br(CH2)10OH, and any needed organic compounds or inorganic reagents.
- Draw the product formed when phenylacetic acid (C6H5CH2COOH) istreated with following reagent. With some reagents, no reaction occurs. CH3OH, H2SO42,3-Dimethylfumaric acid has a molecular formula C6H8O4. It undergoes oxidativecleavage to form two identical compound N. Compound N is then reacted withethylmagnesium bromide to form compound O. Compound O is then hydrolysed inacidic condition to form compound P. Draw the structure of compound N, O and P. PLEASE PROVIDE CLEAR HANDWRITING, and explantionName the following carboxylic acid derivatives, giving both a common name and anIUPAC name where possible.(a) PhCOOCH2CH(CH3)2