Answered: Phosgene, a substance used in poisonous…

Chemistry: Principles and Reactions

8th Edition

ISBN:9781305079373

Author:William L. Masterton, Cecile N. Hurley

Publisher:William L. Masterton, Cecile N. Hurley

Chapter3: Mass Relations In Chemistry; Stoichiometry

Section: Chapter Questions

Problem 51QAP: Write a balanced equation for (a) the combustion (reaction with oxygen gas) of glucose, C6H12O6, to...

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Phosgene, a substance used in poisonous gas warfare during World War I, is so named because it was first prepared by the
action of sunlight on a mixture of carbon monoxide and chlorine gases. Its name comes from the Greek words phos (light) and
genes (born of). Phosgene has the following elemental composition: 12.14% C, 16.17% O, and 71.69% Cl by mass. Its molar
mass is 98.9 g>mol. (a) Determine the molecular formula of this compound. (b) Draw three Lewis structures for the molecule
that satisfy the octet rule for each atom. (The Cl and O atoms bond to C.) (c) Using formal charges, determine which Lewis
structure is the dominant one. (d) Using average bond enthalpies, estimate ΔH for the formation of gaseous phosgene from
CO(g) and Cl21g2.

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