Possible mechanistic intermediates (A - I) are shown directly below - the five correct missing intermediates are contained within this group of structures.
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- 5 a) For each of the reactions below, describe a suitable reaction mechanism, stating the reaction conditions and naming the major productsi) Nitrobenzene and Chloromethaneft) 2-chloro-2-methyl propane and aqueous potassium hydroxide.iii) Propanone and hydrogen cyanide.iv) iodoethane and sodium hydroxide in ethanol.b) i) Discuss the bonding and extra.stability of benzene,ii) Using suitable examples, compare the reactivity of benzene and ethane,Conformation control of reaction mechansims. Consider the reaction below: Provide all possible elimination products from this reaction and identify the major elimination product. Provide mechanisms (with curved arrows) that clearly explain the reaction outcome.When 2,2-dibromo-1-phenylpropane is heated overnight with sodium amide at 150 °C, the major product (after addition of water) is a different foul-smelling compound of formula C9H8. Propose a structure for this product, and give a mechanism to account for its formation.
- predict the main product for the addition of 1 equivalent of HX to the following compounds and write the mechanism of the reactionAcid-catalyzed dehydration of neopentyl alcohol, (CH3)3CCH2OH, yields 2-methyl-2- butene as the major product. Outline a mechanism showing all steps in its formation.(ii) The elimination reaction between 2-bromobutane and NaOCH2CH3 gives two organic products. Draw a mechanism for the reaction which produces the major organic elimination product and provide a rationale as to why that is the major product.
- Predict the products and mechanisms of the following reactions. When more than oneproduct or mechanism is possible, explain which are most likely.(a) 1@bromohexane + sodium ethoxide in ethanol(b) 2@chlorohexane + NaOCH3 in methanolThe following sequence of steps (R)- 2-octanol to (S)- 2-octanol. Propose structural formulas for intermediates A y B, specify the absolute configuration of each, and account for the inversion of configuration in this sequenceTwo chemists at Dupont found that ICH2ZnI is better than diazomethane at converting a C=C bond to a cylcopropane ring. Propose a mechanism for the reaction, now known as the Simmons–Smith reaction in their honor.
- Write the product of the reaction below and the mechanism of its formation. The solvent is benzene and a catalytic amount of HCl is present. Show movement of electrons as curved arrows and show the charges on all intermediates and location of 18O.Can you do 5,6,7 and explain it? State the mechanism in which through reaction proceeds sn2 or sn1 and can you explain the process of the mechanismFor each reaction below, provide the structural formula for the reactants and the predicted products. Indicate which mechanism the reaction will follow and use curved arrow formalism to illustrate the predicted reaction mechanism. t-butylalcohol + NaBr ?