PRACTICE PROBLEM 22-4: Using the data in Table 22.1, calculate the solubility in grams per liter at 25°C of Ag,CrO,(s) in an aqueous solution that is 0.65 M in AgNO3 (ag), which is a strong electrolyte.
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Answer: 8.6 × 10−10 g/L
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- Develop two methods to quantify Ag+, firstly using acid-base equilibria and then redox equilibria. Specify the reagents used in the method and the concentrations of each (Consider the analite concentration: 0.02M ).You are a chemist, you know that in the analysis for total hardness, formation of Ca-EDTA complex in the presence of magnesium-calmagite indicator or Mg-Ind complex involves the following process: Based on the chemical reactions provided, what is equivalent to KMg-Ind?A scientist was tasked to extract Fe from an aqueous suspension that contains 106 g of Fe2O3. The following steps detail the transformation of Fe2O3 (aq) to elemental iron: I. Enough sulfur trioxide gas was bubbled to Fe2O3 aqueous suspension to completely yield ferric sulfate. II. Then, 5.00 M nitric acid was added to ferric sulfate yielding an aqueous solution of ferric nitrate. III. Excess magnesium powder was added to the aqueous solution of ferric nitrate precipitating the solid iron ----- a. Write the balanced chemical reaction and the type of chemical reaction for [I], [II], [III]. Do not forget to indicate the states of the reactants and products (s, l, g).(CHOICES: COMBINATION, SINGLE DISPLACEMENT, DOUBLE DISPLACEMENT) b. What is the final mass of iron? Express final answers in 3 significant figures. c. High-concentration HCl is supposed to be added at the last part of the procedure. Briefly state its purpose.
- Give a brief introduction on proton coupled electron transfer equilibria (PCET) explaining what cyclic voltammetry is in relation to oxidation and reduction, transfer of electrons and how the Nernst equation is appliedYou are a chemist, you know that in the analysis for total hardness, formation of Ca-EDTA complex in the presence of magnesium-calmagite indicator or Mg-Ind complex involves the following process: Based on the chemical reactions provided, what is equivalent to the overall concentration of Mg-EDTA near its endpoint?The concentration of ammonia in a cleaning product was determined by back titration.Firstly, 10.00 cm3 of the cleaning product was pipetted into a large conical flask,containing 250.00cm3 of 0.50 mol/l HCl to give Solution A.Following a period of reaction and shaking, 50.00cm3 of Solution A was removed anddiluted to 250 cm3 with water in a volumetric flask to give Solution B.20 cm3 samples of Solution B were titrated against 0.05 mol/l Na2CO3 solution, givingan average titre of 12.45 cm3. i) Write equations for the reactions that have taken place.ii) Determine the concentration of NH3 in the original cleaning product in mol/l,g/l, ppm, and % w/v.
- complex formation equilibria with Ag+ for EDTA, CN-, NH3, I-Determine the solubility of KIO4 in water. Volume of saturated KIO4 in conical flask is 25.0 ml,KI is 2g,H2SO4 (3.0M) is 20.0 ml added to KI solution , volume of 0.200 M sodium thiosulphate used for titration is 8.00 ml.and if mean ionic activity co efficient,y+- of KIO4 in the saturated solution is 0.85 ,what is Ksp. .Using activities,(a) Find the concentration of of hydroxide ion in 0.10 M NaClO 4 saturated with Mn(OH)2(Ksp = 1.6 x 10 –13 ).(b) Determine the pH of the solution at 25 ̊C if Kw is 1.0 x 10 –1
- A second calibration standard solution of an iron(III) salicylate complex was prepared in two steps. First, 12.9 mL of a 0.481 M stock solution was diluted with solvent to make 100.0 mL of the first calibration standard solution and, secondly, 86.6 mL of that first calibration solution was diluted to 100 mL to make the second calibration standard. What is the molar concentration of the second calibration standard solution? Report your answer to 3 significant figures.You are investigating the presence of iodine in the otherwise clean waste of a chemical treatment facility (assume no matrix effects). First, you oxidize the I- to I2 (assume a 2 I- to 1 I2 stoichiometry) and then you form a bright green complex with the I2 using toluene (assume a 1 I2 to 1 I2-toluene complex stoichiometry). The molar absorptivity of the complex is 7.87 * 104 M-1 cm-1 at 635 nm. When performing this process using a 1.00-cm cuvette with a sample from the facility, you obtained an absorbance of 0.665. What is the concentration of I- in the facility's sample? Report your answer in M and place your answer in scientific notationAt 25°C the equivalent conductivities of dilute NaI solutions are as following:Find Λ° of NaI at 25°C