Problem 1: In statistical mechanics, the internal energy of an ideal gas is given by: N 2/3 2S U = U(S, V) = aNkB 3NKB e where a is a constant. 1- Show that the variation of the internal energy is given by: (s, ") as - Gu). 2 U).dV 3V dU = .dS - 3M 2- Using the fundamental relation of thermodynamic dU = T.ds – p.dV, show that the equation of state PV = nRT follows from the first expression of U.
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