Problem 42 IR Spectrum (liquid film) 4000 3000 2000 1600 1200 800 v (cm') 100 121 Mass Spectrum 80 60 40 M+= 152 20 40 80 120 160 200 240 280 m/e 13C NMR Spectrum (100.0 MHz, CDCI, solution) expansion solvent 130 128 ppm proton decoupled 200 160 120 80 40 8 (ppm) 1H NMR Spectrum (400 MHz, CDCI, solution) expansion 7.6 7.4 ppm TMS 1 8 (ppm) 10 7 4 3 2 of base peak

Principles of Instrumental Analysis
7th Edition
ISBN:9781305577213
Author:Douglas A. Skoog, F. James Holler, Stanley R. Crouch
Publisher:Douglas A. Skoog, F. James Holler, Stanley R. Crouch
Chapter17: Applications Of Infrared Spectrometry
Section: Chapter Questions
Problem 17.1QAP: Cyclohexnone exhibits its strongest IR absorption hand at 5.86 m, and at this wavelength there is a...
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Problem 42
IR Spectrum
(liquid film)
4000
3000
2000
1600
1200
800
V (cm')
100
121
Mass Spectrum
80
60
40
M+= 152
20
40
80
120
160
200
240
280
m/e
13C NMR Spectrum
(100.0 MHz, CDCI, solution)
expansion
solvent
130 128 ppm
proton decoupled
200
160
120
80
40
8 (ppm)
H NMR Spectrum
(400 MHz, CDCI, solution)
expansion
7.6 7.4
ppm
TMS
1
8 (ppm)
10
9.
7
6.
5
4
3
% of base peak
Transcribed Image Text:Problem 42 IR Spectrum (liquid film) 4000 3000 2000 1600 1200 800 V (cm') 100 121 Mass Spectrum 80 60 40 M+= 152 20 40 80 120 160 200 240 280 m/e 13C NMR Spectrum (100.0 MHz, CDCI, solution) expansion solvent 130 128 ppm proton decoupled 200 160 120 80 40 8 (ppm) H NMR Spectrum (400 MHz, CDCI, solution) expansion 7.6 7.4 ppm TMS 1 8 (ppm) 10 9. 7 6. 5 4 3 % of base peak
Unknown Spectroscopy Practice Problems: Problem #42
Molecular formula & DU:
What is the structural basis for the 'H NMR signal at 3.4 ppm?
Proposed structure:
Transcribed Image Text:Unknown Spectroscopy Practice Problems: Problem #42 Molecular formula & DU: What is the structural basis for the 'H NMR signal at 3.4 ppm? Proposed structure:
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