Propose a structure for an amine of formula C,H,N, which liberates a gas when treated with NaNO, and HCl. The 13C NMR spectrum is given, with attached protons in parentheses. 13C NMR: 8 14 (2), 8 34.3 (2), 8 50.0 (1)

Propose a structure for an amine of formula C,H,N, which liberates a gas when treated with NaNO, and HCl. The 13C NMR spectrum is given, with attached protons in parentheses. 13C NMR: 8 14 (2), 8 34.3 (2), 8 50.0 (1)

Organic Chemistry

8th Edition

ISBN:9781305580350

Author:William H. Brown, Brent L. Iverson, Eric Anslyn, Christopher S. Foote

Publisher:William H. Brown, Brent L. Iverson, Eric Anslyn, Christopher S. Foote

Chapter13: Nuclear Magnetic Resonance Spectroscopy

Section: Chapter Questions

Problem 13.17P: Following are 1H-NMR spectra for compounds G, H, and I, each with the molecular formula C5H12O. Each...

See similar textbooks

Related questions

Q: An attempt was made to dissolve 5.893 grams of PbCl2 in 1.000 liters of water. The Ksp of PbCl2 is 1...

Q: Bi(0TH)3-41-0 R-OH + BiloTfb-4rb0. R-0M DMF /MeDH 0. R-OAU R-0THP + DCM

A: In organic synthesis, the THP group is used as the protecting group for alcohols.

Q: Use the following graphs to answer the question below. А. В. С. y y y X X Identify the graph that be...

Q: 436.4 kJ/mol H2(g) → 2H(g) Br2(g) → 2Br(g) H2(g) + Br2(g) ΔΗ ΔΗ 192.5 kJ/mol 2HBr(g) AH° = –72.4 kJ/...

A: H(g) + Br(g) ---> HBr(g)

Q: A 24 year old graduate student was brought to the ED in a comatose state after being found unconsiou...

Q: How many moles of sodium hydroxide would have to be added to 125 mL of a 0.339 M hypochlorous acid s...

Q: The structure of an amine is shown. R- Indicate whether the amine, where R is a phenyl group, can ex...

Q: °C, the capillary rise at sea level for th air in a tube with inside diameter 0. e contact angle is ...

Q: Exp. 2:Determine the Enthalpy of Neutralization of HCI by NH3 Temp of empty calorimeter= 21.5C, calo...

A: a.) q (heat) can be calculated using formula : q = m × C × ∆T b.) ∆H for a reaction is written i...

Q: Can you always rank molar solubilities by ranking Ksp values? Explain your answer. Begin your answer...

A: A question based on solution that is to be accomplished.

Q: Unknown # Draw the flow chart for this experiment and record you observations for Use two different ...

Q: Problem 1. Derive an expression and calculate a numerical value for the lifetime in seconds for the ...

A: We have find out numerical value for the life time in seconds.

Q: There are several equations given below. Which equation can be used to find the standard entropy cha...

A: We have given several equations to find standard entropy change (∆S°). We need to tell which one amo...

Q: Study the reactions. I. N2(g) + O2(g) → 2NO(g) II. CO(9) + O2(9) → 2CO2(9) III. Na(s) + HCI(1) → 2Na...

A: To choose correct option , we would check phase of species in reactions.

Q: The pH of a 0.10 MM solution of formic acid (HCO2H) is 2.38. Calculate Ka for formic acid. Calculat...

A: We have 0.10 M of formic acid whose pH is given we have to predict the Ka and Pka.

Q: Consider the reaction: HC6H6O6- + NH4OH = NH4C6H6O6- + H2O Which of the following is not true? A...

A: Acid is species which donate hydrogen atom and base is species which accept hydrogen.

Q: Note: I need a simple explanation for this lesson for my presentation. Thank you!

A: Polymers are composed of many small repeating units (monomer) joined together. Polymers having hig...

Q: In the future, metals may be discovered that are even softer than very soft metals such as Au or Hg....

A: The HSAB principle put forward by Pearson states that, soft acids react faster and form stronger bon...

Q: Please do this question and show your steps.

A: We have to tell the answers.

Q: What is the molarity of a solution made when 10 kg of Sugar are dissolved to make 100 liter solution

A: As per bartleby guidelines I answered only first question so please don't mind.Thanks in advance.

Q: Consider the titration of 50.0 mL of 0.501 M weak base B (Kb = 7.5 x 10⁻⁶) with 0.340 M HNO₃. What i...

Q: Compare the two quantities based on the given condition: A solution containing Ba2+ and trace amount...

A: Here a given solution containing Ba+2 and trace amount of Ca+2 is precipitated as BaSO4. We have to...

Q: For the enzyme-substrate reaction, E + S=ES E+ P, a 96-well plate assay is used to screen a libriay ...

A: Correct option is Negative control to confirm that the product can be detected in the presence of en...

Q: D. What is the average rate constant? Indicate the appropriate units. E. What is the energy of activ...

A: Before finding the average rate constant, we have to find the order of the reaction with respect to ...

Q: Give the chemical reaction in standardizing Potassium dichromate using standardized Sodium thiosulfa...

A: In standardization of K2Cr2O7 , there are two step in reaction . First K2Cr2O7 is mixed with KI , H...

Q: 1. The rotation constant for H2 is 60.80 cm-1 , the harmonic frequency is 4395.3 cm-1 and the anhar...

Q: A student measures the S2- concentration in a saturated aqueous solution of cobalt(II) sulfide to be...

Q: Below what temperature does the following reaction become spontaneous? FeO(s) + CO(g) → CO2(g) + Fe(...

Q: Q2: Calculate the solubility of Mg(OH)2 in 0.10 M NaOH.Calculate the solubility in grams/liter (use ...

A: Since you have asked multiple questions, we will solve the first question for you. If you want any s...

Q: Show how to carry out the transformation of benzene to chlorobenzene by going through a diazonium in...

A: In this question, we have to carry out the conversion of benzene to chlorobenzene by going through a...

Q: Acid Names IUPAC HCN(aq) Classical Acid Names IUPAC HCIO2(aq) Classical Acid Name IUPAC CH3COOH(aq) ...

A: IUPAC name is the systematic name given to a chemical compound International Union of Pure and Appli...

Q: Calculate the pH when 77.0 mL of 0.250 M HCI is mixed with 40.0 mL of 0.150 M Ca(OH):.

Q: TRUE OR FALSE; The carbonyl carbon in an amide and the carbon in an aromatic ring have the same hybr...

A: The hybridisation of a particular carbon atom in a compound can be found out easily as follows, ...

Q: Reset Help Bronsted-Lowry acid Bronsted-Lowry base NH3(aq) H20(I) NH,*(aq) + OH (aq) conjugate acid ...

Q: Provide the rest of the mechanism for this electrophilic addition reaction.

Q: Determine the equilibrium constant K_{p} at 25°C for the reaction N 2 (g) 3H 2 (g) cong2NH 3 (g); [ ...

Q: The spin and parity of J/psi meson J/y : JP О а. 1 O b. 1* Oc. 0* 33 d. 0

A: Concept: The J/ψ(J/psi) meson or psion is a type of subatomic particle. It is a flavor-neutral meson...

Q: How could you modify the structure of p-toluenesulfonic acid to lower its pKa

Q: List the types of intermolecular forces that exist between molecules (or basic units) in each of the...

Q: A chemist dissolves 197. mg of pure sodium hydroxide in enough water to make up 170. mL of solution....

Q: The following chemical reaction takes place in aqueous solution: SnCl,(aq)+2 NaOH(aq)Sn (OH),(s)+2 N...

Q: Question 8 of 15 Consider the equilibrium system described by the chemical reaction below. If 0.1908...

Q: How many grams of AgNO 3 (molar mass = 169.87 g/mol) are needed to prepare 0.125M solution in 250 mL...

A: Given - Molarity = 0.125 M Molar mass = 169.87 gm.mole-1 Volume = 250 ml = 0.250 L (1L = 1000ml)

Q: Write the formula for the conjugate acid of each of the following bases.

A: Conjugate acid is the chemical species formed when Bronsted Lawry Base accepts a proton. when writin...

Q: Trial 1 Trial 2 Mass of ice Mce (grams) 79 79 Mass of warm water 120 119 Mwater (grams) Initial temp...

A: The amount of heat lost by the hot body is equal in amount of the heat absorbed by the cold body. Th...

Q: to E°Ag = 0.799V, E° Zn M), and Zn/Zn2+ (1.0 M) half cells, %3D Questions Consider the reaction: SO2...

Q: A. The molar solubility of silver iodide in a 0.214 M silver acetate solution is _____? B. The maxi...

Q: SUOUE Unknown # 34 Draw the flow chart for this experiment and record you observations for each step...

A: We have to analysis group III Cations.

Q: Define the following: A. Extraction B. Infusion

A: Analytical chemistry is branch of chemistry in which we deal with instruments and methods used to se...

Q: Compare the two quantities based on the given condition: Ten (10) mL of solution X contains 0.100 M...

A: Here 10 ml of solution containing 0.1 M each of HCl and HA (pKa =5) and in other case 10 ml of solut...

Concept explainers

NMR Spectroscopy

NMR stands for Nuclear Magnetic Resonance in which the study of different molecules is done based on the interaction of radiofrequency electromagnetic radiations with the nuclei of molecules placed in a strong magnetic field. A precise study of spectra of visible light and all bands of electromagnetic radiation is called spectroscopy.

Question

100%

Loudon | Parise SEVENTH EDITION
presented by Macmillan Learning
Propose a structure for an amine of formula C,H,N, which liberates a gas when treated with NaNO, and HCl. The 13C NMR
spectrum is given, with attached protons in parentheses.
13C NMR: 8 14 (2), 8 34.3 (2), 8 50.0 (1)

Expert Solution

This question has been solved!

Explore an expertly crafted, step-by-step solution for a thorough understanding of key concepts.

SEE SOLUTION Check out a sample Q&A here

Step 1

Step 2

Step 3

Step 4

Step 5

Step by step

Solved in 5 steps with 2 images

SEE SOLUTION Check out a sample Q&A here

Knowledge Booster

Learn more about

Need a deep-dive on the concept behind this application? Look no further. Learn more about this topic, chemistry and related others by exploring similar questions and additional content below.

Similar questions

A 13C NMR spectrum of commercially available 2,4-pentanediol, shows five peaks at 23.3, 23.9, 46.5, 64.8, and 68.1 . Explain.
1H NMR spectrum is shown below. Is it an ester found in wintergreen oil or an ester that is commonly used as a pain reliever. Both esters can be made from salicylic acid. Based on this information, determine the structure/identity of the ester corresponding to Spectrum 1.
1) Propose the structures for the following 1H and 13C NMR spectrum. b) Molecular Formula: C8H8O3 1H-NMR, CDCl3 Solvent, Molecular Formula: C8H8O3 13C-NMR, CDCl3 Solvent, Molecular Formula: C8H8O3 in the pictures
A chemist records an ESI accurate mass spectrum of an intermediate during a synthesis. The desired compound is C29H31N3O8S. She sees a peak(M+H)^(+) on her ESI-TOF LCMS at 583.1733. The two possibilites for the incorrect feature are A: incoporation of a deuterium at an acidic site from the CDCL3 used for NMR she ran immedately prior LC-MS or B: An amide was hydrolyzed to an acid. Assuming the mass spectrometer is well calibrated, which of these two options is supported by the data. Be sure to explain your answer.
The compound with the closed formula C4H9Br gives the following 1H NMR data. Write the clear formula of the compound with reasons. 1.0 ppm (triplet, 3 H); 1.7 ppm (dublet, 3H); 1.8 ppm (multiplet, 2H); 4.2 ppm (multiplet, 1H)
1) Propose the structures for the following 1H and 13C NMR spectra. a) Molecular Formula: C5H10O2 1H-NMR, CDCl3 Solvent, Molecular Formula: C5H10O2 13C-NMR, CDCl3 Solvent, Molecular Formula: C5H10O2 in the pictures
Which of the diethylbenzene isomers (ortho, meta, or para) correspondsto each set of 13C NMR spectral data ? 13C NMR signals: 16, 29, 128, and 141 ppm
The 1H- and 13C-NMR data of an ester of molecular formula C6H10O2 are given below. Also shown are the COSY and HETCOR NMR spectra of the ester. Draw the structure of the ester, explaining how you reach your conclusion. 1H-NMR: 7.20-6.90 (1H), 5.85 (1H), 4.16 (2H), 1.88 (3H), 1.31 (3H) ppm 13C-NMR: 166.7, 144.5, 123.0 , 60.2, 18.0, 14.3 ppm
Show the 13C NMR for the following compound and Explain each peak for formed in detail.
what compound is this cnmr and nmr which is a solid and has a boiling point of 47.8 - 124.3 degrees celsius
QUESTION 9 Propose a structure for a carboxylic acid with molecular formula C6H10O2 by interpreting the following 13C NMR spectra.
an unknown compound of molecular formula C4H10O only showed singlets in its 1H-NMR