Answered: Q2 Propose mechanisms for the following…

Q2 Propose mechanisms for the following reactions. (a) (b) (c) (d) (e) Br HBr ROOR hv cat. H₂SO4 H₂O HBr HCI EtOH cat. H₂SO4 H₂O Br OH Br Br CH₂CH3 H -OH H -OH CH₂CH3 + + Br Br

Organic Chemistry

9th Edition

ISBN:9781305080485

Author:John E. McMurry

Publisher:John E. McMurry

Chapter22: Carbonyl Alpha-substitution Reactions

Section22.SE: Something Extra

Problem 26MP: Nonconjugated , -unsaturated ketones, such as 3-cyclohexenone, are in an acid-catalyzed equilibrium...

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Concept explainers

Aromatic Compounds

Aromatic organic compound or aromatic system is an important class of hydrocarbons under the branch of organic chemistry. Aromatic compounds are also called arenas. The definition of aromatic organic compounds can be stated as a class of organic compounds with a planar cyclic ring of atoms bonded through alternated single and double bonds. Due to these alternating bonds, a peculiar feature termed as ‘resonance’, that is, delocalization of pi electrons or the electrons is shared within the atoms of the ring which are present in the aromatic compounds. The word ‘aromatic’ includes a Greek word ‘aroma’ which means smell, indicating that they were named as such due to the sweet odor they produce. Many well-known flavors such as vanilla, cinnamon, and few scents from flowers are extracted from aromatic compounds. Benzene with chemical formula C6H6 is a very common aromatic compound that contains six atoms of carbon held in the cyclic ring of alternate double bonds. It is also to be noted that not all aromatic compounds contain benzene ring. This can be explained by Huckel’s rule.

Question

Q2 Propose mechanisms for the following reactions.
(a)
(b)
(c)
(d)
(e)
Br
HBr
ROOR
hv
cat. H₂SO4
H₂O
HBr
HCI
EtOH
cat. H₂SO4
H₂O
Br
♡on
Br
Br
CH₂CH3
H -OH
H
-OH
CH₂CH3
+
Br
Br

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