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- 1. Discuss the role of the Aldol condensation reaction in the synthesis below. What specific reaction was used in the synthesis? What is the importance of the aldol reaction in the entire synthetic approach? 2. Show the detailed reaction mechanism involved in their corresponding specific parts in this syntheses.Provide the mechansim using curved arrows of the reaction of p-t-butyl phenol treated with acetic anhydride in AlCl3. Include resonance stabilized intermediates and if more than one product is formed, label them as major, minor, etc. thank you for the helpgive tha three synthesis with mechanism of triazolo(1,5-a) pyridines and 5-triazolo(3,4-b)1,3,4dithiazolo
- (a) Account for the following :(i) CH3CHO is more reactive than CH3COCH3 towards reaction with HCN.(ii) Carboxylic acid is a stronger acid than phenol.(b) Write the chemical equations to illustrate the following name reactions:(i) Wolff-Kishner reduction (ii) Aldol condensation (iii) Cannizzaro reactionPlease describe the difference in the outcome of treating a terminal alkyne with HgSO4, H2SO4, H2O and with 9-BBN, followed by H2O2 and NaOH.Like other strong nucleophiles, triphenylphosphine attacks and opens epoxides. Theinitial product (a betaine) quickly cyclizes to an oxaphosphetane that collapses to analkene and triphenylphosphine oxide.(a) Show each step in the reaction of trans-2,3-epoxybutane with triphenylphosphine togive but-2-ene. What is the stereochemistry of the double bond in the product?(b) Show how this sequence might be used to convert cis-cyclooctene to trans-cyclooctene
- Like other strong nucleophiles, triphenylphosphine attacks and opens epoxides. Theinitial product (a betaine) quickly cyclizes to an oxaphosphetane that collapses to analkene and triphenylphosphine oxide.(a) Show each step in the reaction of trans-2,3-epoxybutane with triphenylphosphine togive but-2-ene. What is the stereochemistry of the double bond in the product?For butenafine, develop a synthesis that starts with napthalene and benzene. (aromatic methyl groups can be converted to alkyl bromides using Br2/light, and aldehydes by heating the alkyl bromide in DMSO, eg. ArCH3 to ArCH2Br then to ArCHO).Two possibilities for a Wittig synthesis of the compound below involve using: 1)cyclohexanone and ethyl bromide or 2) bromocyclohexane and ethanal. Is either routebetter, and if so, why is one superior? Be specific and explain where the difficulty lies forthe inferior route
- Compelling evidence for the existence of a tetrahedral intermediate innucleophilic acyl substitution was obtained in a series of elegantexperiments carried out by Myron Bender in 1951. The key experimentwas the reaction of aqueous −OH with ethyl benzoate (C6H5COOCH2CH3)labeled at the carbonyl oxygen with 18O. Bender did not allow thehydrolysis to go to completion, and then examined the presence of alabel in the recovered starting material. He found that some of therecovered ethyl benzoate no longer contained a label at the carbonyloxygen. With reference to the accepted mechanism of nucleophilic acyl substitution, explain how this provides evidence for a tetrahedralintermediate.Which of the following will give just 1 product when reacted with a Grignard reagent (R-MgBr)? asymmetric ketone ?,? -unsaturated ketone generic aldehyde symmetric ketoneWhy do you suppose ketone halogenations in acidic media are referred to as being acid-catalyzed, whereas halogenations in basic media are base-promoted? In other words, why is a full equivalent of base required for halogenation?