Question 12 Please predict the products for each of the following reactions. Clearly show the regiochemistry (Markovnikov vs anti-Markovnikov) and stereochemistry (syn- vs anti- or both). If a mixture of enantiomers is formed, please draw all the enantiomers. Br₂ CH₂OH 1.03 2. DMS KMnO4, NaOH cold HI MCPBA 1. OsO4 2. H₂O₂ 19 18 17 16 15 CH3CO₂H (peroxyacid) 14 13 A OH фон кон OH A B C D Pd or Pt (catalyst) 20 1 2 ROOR HBr H₂SO4 HCI 8 12 11 10 Br FIOH D₂ (deuterium) B 1. BH3.THF 2. H2O2, NaOH Br2 Br2 H₂O BH3⚫THF с D OH OH OH "OH OH "OH OH OH OH OH OH OH 'OH OH "OH OH OH
Question 12 Please predict the products for each of the following reactions. Clearly show the regiochemistry (Markovnikov vs anti-Markovnikov) and stereochemistry (syn- vs anti- or both). If a mixture of enantiomers is formed, please draw all the enantiomers. Br₂ CH₂OH 1.03 2. DMS KMnO4, NaOH cold HI MCPBA 1. OsO4 2. H₂O₂ 19 18 17 16 15 CH3CO₂H (peroxyacid) 14 13 A OH фон кон OH A B C D Pd or Pt (catalyst) 20 1 2 ROOR HBr H₂SO4 HCI 8 12 11 10 Br FIOH D₂ (deuterium) B 1. BH3.THF 2. H2O2, NaOH Br2 Br2 H₂O BH3⚫THF с D OH OH OH "OH OH "OH OH OH OH OH OH OH 'OH OH "OH OH OH
Chapter9: Alkynes: An Introduction To Organic Synthesis
Section9.SE: Something Extra
Problem 46AP: A hydrocarbon of unknown structure has the formula C8H10. On catalytic hydrogenation over the...
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