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Predict the products of the following reaction:
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- A chemist allows some pure (2S,3R)-3-bromo-2,3-diphenylpentane to react with a solution of sodium ethoxide(NaOCH2CH3) in ethanol. The products are two alkenes: A (cis-trans mixture) and B, a single pure isomer. Under thesame conditions, the reaction of (2S,3S)-3-bromo-2,3-diphenylpentane gives two alkenes, A (cis-trans mixture) and C.Upon catalytic hydrogenation, all three of these alkenes (A, B, and C) give 2,3-diphenylpentane. Determine the structuresof A, B, and C; give equations for their formation; and explain the stereospecificity of these reactions(10pts) Compound A, C10H16, was found to be optically active. On catalytic reduction over a palladium catalyst, 2 equivalents of hydrogen were absorbed, yielding compound B, CioH2o. On ozonolysis of A, two fragments were obtained. One fragment was identified as acetic acid (CHCOOH). The other fragment, compound C, was an optically active carboxylic acid, C8H14O2. Write reactions, and draw the correct structures for A-C, explain your answer in detail.A chemist allows some pure (2S,3R)-3-bromo-2,3-diphenylpentane to react with a solution of sodium ethoxide(NaOCH2 CH3) in ethanol. The products are two alkenes: A (cis-trans mixture) and B, a single pure isomer. Under the same conditions, the reaction of (2S,3S)-3-bromo-2,3-diphenylpentane gives two alkenes, A (cis-trans mixture) and C. Upon catalytic hydrogenation, all three of these alkenes (A, B, and C) give 2,3-diphenylpentane. Determine the structures of A, B, and C; give equations for their formation; and explain the stereospecificity of these reactions.
- Which structure will not yield cis- or trans- isomers after a reaction with H2/Lindlar catalyst or Na/NH3?What products (including stereoisomers, if applicable) are formed from the reaction of 3-bromo-3-methylpentane: a. with HO-? b. with H2O?I recovered 3 mL of water, how many grams of water was produced in the reaction please show how? Cyclohexanol can attack the carbocation intermediate formed during the synthesis of cyclohexene. Draw this side product with the molecular formula C12H22O.
- reactions and products for C9H8O4 C9H8O4 + O2 --> C9H8O4 + H2O --> C9H8O4 + HCl --> C9H8O4 + OH- --> C9H8O4 + Na --> C9H8O4 + F -->Draw structures for the products formed in the following reactions. If more than one product is possible, show all of them, and indicate the major product, if any.An unknown compound is treated with HBr in the dark. The product of this reaction is reacted with potassium t-butoxide. The product of reaction 2 is treated with HBr and peroxide. In reaction 4 the product of reaction 3 is treated with lithium acetylenide (C2H-). The product of reaction4 is reduced with hydrogen using platinum as a catalyst. This final product was determined to be n-pentylcyclopentane. What is the name of the original unknown compound?
- Starting with cyclohexanone, show how to prepare these compounds. In addition to the given starting material, use any other organic or inorganic reagents as necessary. Q.) 1-MethylcyclohexeneWhat organic product would you obtain from reaction of 1-pentanol with CrO3, H2O, H2SO4?(please answer all questions) 1) Predict the products from reaction of 1-hexyne with thesereagents: a) One equivalent HBr b) One equivalent Cl2 c) H2 , Lindar Catalyst d) NaNH2 in NH3 , then CH3Br