Rate constants for decomposition of gaseous dinitrogen pentoxide are 3.7 x 10-5 s-1 at 25°C and 1.7 x 10-3 s-1 at 55°C. (a) Determine the activation energy for this reaction in kJ/mol. (b) Calculate the rate constant at 35°C. T, : 25°C + 273.15 = 198.15K In(는) Ea k, : 3.7 x 10s-' T: 55°C + 273.15 = 328.15 K -3 : 3.827465l17 -3 kg = 1.7 x 10s' \3.7 x1055-' • 0.00030663 K-' 328-15 K 298. IS K Rin() - (R.314(.827465117) 1.04 x 1o5 * Ea = - 0. 00030663 K* Ea + 104

Chemistry: Principles and Reactions
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Chapter11: Rate Of Reaction
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2 Ng Os lg)
4 NO, l)
+ gly)
Arrhenius Equation: Example
Rate constants for decomposition of gaseous dinitrogen pentoxide are 3.7 x 10-5 s-1 at 25°C and 1.7 x 10-3 s-1 at 55°C.
(a) Determine the activation energy for this reaction in kJ/mol.
(b) Calculate the rate constant at 35°C.
T, : 25°C + 233.15 = 298.15 K
In) :
k, : 3.4 x 10s'
T: 55°C + 273.15 = 328.15 K
1.7 x 10
: 3.827465617
hy : 1.7 x 1os-
3.7x105
• 0.00030663 k-
328-15 K
298. IS K
An (놈)
- (8.314)827465sli7)
Kimol
+ 1.04 x
Ea :
- 0. 00030663 K*
Ea
kJ
+ 10니
Transcribed Image Text:2 Ng Os lg) 4 NO, l) + gly) Arrhenius Equation: Example Rate constants for decomposition of gaseous dinitrogen pentoxide are 3.7 x 10-5 s-1 at 25°C and 1.7 x 10-3 s-1 at 55°C. (a) Determine the activation energy for this reaction in kJ/mol. (b) Calculate the rate constant at 35°C. T, : 25°C + 233.15 = 298.15 K In) : k, : 3.4 x 10s' T: 55°C + 273.15 = 328.15 K 1.7 x 10 : 3.827465617 hy : 1.7 x 1os- 3.7x105 • 0.00030663 k- 328-15 K 298. IS K An (놈) - (8.314)827465sli7) Kimol + 1.04 x Ea : - 0. 00030663 K* Ea kJ + 10니
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