rate of this reaction

Chemistry for Engineering Students
4th Edition
ISBN:9781337398909
Author:Lawrence S. Brown, Tom Holme
Publisher:Lawrence S. Brown, Tom Holme
Chapter11: Chemical Kinetics
Section: Chapter Questions
Problem 11.36PAE: The reaction NO(g) + O,(g) — NO,(g) + 0(g) plays a role in the formation of nitrogen dioxide in...
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The reaction
NO(g) + 02(g) – NO2(g) + O(g)
plays a role in the formation of nitrogen dioxide in automobile engines. Suppose that a series of
experiments measured the rate of this reaction at a certain temperature and produced the following data:
[02]
(mol L1)
[NO]
Rate
Expt
(mol L)
(mol L1s)
1
0.0020
0.0050
5.0 x 1017
2
0.0020
0.010
1.0 x 1016
0.0060
0.0050
1.5 x 1016
A rate = k[NO]°[O2]?
B rate = k[NO][O2]?
C
rate = k[NO]?[02]
D) rate = k[NO][02]
3.
Transcribed Image Text:The reaction NO(g) + 02(g) – NO2(g) + O(g) plays a role in the formation of nitrogen dioxide in automobile engines. Suppose that a series of experiments measured the rate of this reaction at a certain temperature and produced the following data: [02] (mol L1) [NO] Rate Expt (mol L) (mol L1s) 1 0.0020 0.0050 5.0 x 1017 2 0.0020 0.010 1.0 x 1016 0.0060 0.0050 1.5 x 1016 A rate = k[NO]°[O2]? B rate = k[NO][O2]? C rate = k[NO]?[02] D) rate = k[NO][02] 3.
JUST A REMINDER, TAKE NOTE
IN SOLVING
Summary of molecularity of elementary reactions
Type of Elementary Reaction
Molecularity
Rate Law
A→ products
Unimolecular
Rate = k[A]
%3D
A + B → products
2 A→products
Rate
k[A][B]
%3D
Bimolecular
Rate = k[A]²
%3D
A + B + C → products
2 A + B → products
Rate = k[A][B][C]
%3D
Termolecular
Rate = k[A]°[B]
A + B + C + D→ products
The Arrhenius equation describes the temperature
dependence of the rate constant, k.
Not observed
Ea
k = Ae RT
- E, is the activation energy
- R is the universal gas law constant
• Ris 8.314 J mol K
- T is the absolute temperature,
- A is the proportionality constant called the frequency factor or
0.693
t1/2 =
k
preexponential factor.
Transcribed Image Text:JUST A REMINDER, TAKE NOTE IN SOLVING Summary of molecularity of elementary reactions Type of Elementary Reaction Molecularity Rate Law A→ products Unimolecular Rate = k[A] %3D A + B → products 2 A→products Rate k[A][B] %3D Bimolecular Rate = k[A]² %3D A + B + C → products 2 A + B → products Rate = k[A][B][C] %3D Termolecular Rate = k[A]°[B] A + B + C + D→ products The Arrhenius equation describes the temperature dependence of the rate constant, k. Not observed Ea k = Ae RT - E, is the activation energy - R is the universal gas law constant • Ris 8.314 J mol K - T is the absolute temperature, - A is the proportionality constant called the frequency factor or 0.693 t1/2 = k preexponential factor.
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