reaction vessel compound concentration expected change in concentration CH2CH2NH₂ 0.77 M ○ ↑ increase O↓ decrease (no change) HCI 0.78 M ○ ↑ increase ○ ↓ decrease (no change) A Cl 1.31 M ○ ↑ increase O↓ decrease (no change) CH2CH2NH 0.96 M ○ ↑ increase O↓ decrease ○ (no change) CH2CH2NH₂ 0.85 M ○ ↑ increase Odecrease (no change) HCl 0.86 M ○ ↑ increase ○ ↓ decrease (no change) B Cl 0.69 M O↑ increase O↓ decrease (no change) CH3CH2NH 0.43 M ○ ↑ increase O↓ decrease ○ (no change) CH2CH2NH₂ 0.29 M ↑ increase O decrease HCl 0.30 M ○ ↑ increase O↓ decrease с Cl 1.25 M ↑ increase ○ ↓ decrease CH,CH,NH, 0.99 M O↑ increase O↓ decrease (no change) ○ (no change) (no change) ○ (no change)

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Chapter12: Chemical Equilibrium
Section: Chapter Questions
Problem 12.79PAE
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A chemical engineer is studying the following reaction:
CH3CH2NH2(aq) + HCl(aq) → Cl˜¯(aq)+CH¸CH₂NH(aq)
At the temperature the engineer picks, the equilibrium constant K for this reaction is 2.1.
The engineer charges ("fills") four reaction vessels with ethylamine and hydrogen chloride, and lets the reaction begin. She then measures the composition of
the mixture inside each vessel from time to time. Her first set of measurements are shown in the table below.
Predict the changes in the compositions the engineer should expect next time she measures the compositions.
Transcribed Image Text:A chemical engineer is studying the following reaction: CH3CH2NH2(aq) + HCl(aq) → Cl˜¯(aq)+CH¸CH₂NH(aq) At the temperature the engineer picks, the equilibrium constant K for this reaction is 2.1. The engineer charges ("fills") four reaction vessels with ethylamine and hydrogen chloride, and lets the reaction begin. She then measures the composition of the mixture inside each vessel from time to time. Her first set of measurements are shown in the table below. Predict the changes in the compositions the engineer should expect next time she measures the compositions.
reaction
vessel
compound concentration
expected change in concentration
CH2CH2NH₂
0.77 M
○ ↑ increase
○↓ decrease
(no change)
HCl
0.78 M
↑ increase
○ decrease
○ (no change)
A
Cl
1.31 M
↑ increase
Odecrease
CH2CH2NH
0.96 M
○ ↑ increase
○ decrease
CH2CH2NH₂
0.85 M
○ ↑ increase
O↓ decrease
HCl
0.86 M
○ ↑ increase
○ ↓ decrease
B
Cl
0.69 M
↑ increase
Odecrease
CH3CH2NH3
0.43 M
○ ↑ increase
O↓ decrease
CH3CH2NH₂
0.29 M
↑ increase
Odecrease
(no change)
○ (no change)
(no change)
○ (no change)
(no change)
○ (no change)
○ (no change)
HCl
0.30 M
↑ increase
Odecrease
(no change)
C
Cl
1.25 M
↑ increase
Odecrease
○ (no change)
CH,CH,NH,
0.99 M
○ ↑ increase
O↓ decrease
○ (no change)
Transcribed Image Text:reaction vessel compound concentration expected change in concentration CH2CH2NH₂ 0.77 M ○ ↑ increase ○↓ decrease (no change) HCl 0.78 M ↑ increase ○ decrease ○ (no change) A Cl 1.31 M ↑ increase Odecrease CH2CH2NH 0.96 M ○ ↑ increase ○ decrease CH2CH2NH₂ 0.85 M ○ ↑ increase O↓ decrease HCl 0.86 M ○ ↑ increase ○ ↓ decrease B Cl 0.69 M ↑ increase Odecrease CH3CH2NH3 0.43 M ○ ↑ increase O↓ decrease CH3CH2NH₂ 0.29 M ↑ increase Odecrease (no change) ○ (no change) (no change) ○ (no change) (no change) ○ (no change) ○ (no change) HCl 0.30 M ↑ increase Odecrease (no change) C Cl 1.25 M ↑ increase Odecrease ○ (no change) CH,CH,NH, 0.99 M ○ ↑ increase O↓ decrease ○ (no change)
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