[RhCl3]       RhCl3 & [RhHCl3(PMe3)2]¯       [RhHCl3(PMe3)2]¯       [RhHCl3]3¯

Q: INORGANIC CHEMISTRY II Differentiate the following complexes [PtCl4]2-, [PtCl3(PMe3)]-,…

A: The isomers which have a restricted rotation around the double bond is known as geometrical isomers.…

Q: Explain why the complex [Fe(H2O)6]3+ has Do = 14,000 cm-1, while [Fe(H2O)6]2+ has Do = 9,350 cm-1.

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Q: What is ligan

A: The word ligand comes from the Latin term that means "to bind." A ligand is an ion or molecule that…

Q: Which ligand below gives the LEAST stability to Pd2+ in forming a square planar complex? О а. NH3 O…

A: a) NH3 will form the least stable complex.  Because we know that more is the basicity of lignad more…

Q: Association reaction is the only pathway for ligand substitution in a square planar complex because…

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Q: The

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Q: Condition: Color intensity of the complex Fe³+ (aq) + SCN (aq) Fe(SCN)²+ I. addition of 0.2M AgNO3…

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Q: Which of the following statements about 10Dq is false? A. [VCl6]2- has a greater 10Dq than [VCl4]…

A: 10Dq is the splitting energy .  As there is strong field ligans sorroundinh the central atom , then…

Q: It refers to addition of auxiliary ligand that potentially forms highly stable complexes with the…

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Q: Determine the d electron configurationof [Os(phen)3]3+complex. A) (t2g)3(eg)0 B) (t2g)5(eg)0 C)…

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Q: The reaction of (Ti(co).]* and chlorotriphenylmethane, Ph,CCI, results in rapid oxidation of…

A: Given information,

Q: Polydentate ligands almost always form ring like structures with the central metal ion. If crowding…

A: EDTA4- is a hexadentate ligand with 4 -CH2-COO- and 2 N atoms of -N-CH2CH2N- as the 6 electron pair…

Q: By using valence bond theory and ligand field theory, prove that [Ru(OMe)2(PMe3)4] is a paramagnetic…

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Q: Name the following compounds, using the standard nomenclature rules for coordination complexes. i)…

A: PPh3 is neutral ligand; hence Au is in the +1 oxidation state. Name : [Au(PPh3)3]+ :…

Q: Compounds with lone pair of electrons are able to form complexes via the donation of electrons…

A: To donate electrons pair, the molecule should have a negative charge or a lone pair of electrons.…

Q: Calculate the electron in the following complexes. a,b,c,d

A: We have given that  Calculate the electron in the given complexes.

Q: According to the Crystal Field Theory, in an octahedral complex the energy levels of the orbitals….…

A: Concept is based on crystal field theory:

Q: Which complex undergoes the slowest ligand exchange of ligands at room temperature A) [Fe(H2O)e]**…

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Q: C3H§M(CO); (M: transition metal) complex obey the 18 electron rules. Draw two possible ture for…

A: Transition elements are elements which have partially filled d orbitals. International Union for…

Q: Which d orbital on M is capable of having a bonding interaction with the ligand group orbital shown?

A: Ligands are the chemical species which have the ability to donate electron pairs.  Metals accept…

Q: In the following complex compound, there are d-electrons.

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Q: 3. Which complex shows lower C-O stretching frequency, [Ni(acac)2(H2O2 or [Ni(acac)2]? Explain.

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Q: Determine the d electron configurationof [OsCl6]3-complex. A) (t2g)4(eg)2 B) (t2g)5(eg)0 C)…

A: Complex = [OsCl6]3- Here Os is present in +3 oxidation state.  Electronic configuration of Os(Z=76)…

Q: 54. In the octahedral complex Co(NH2CH2CO2)3, each glycinate ion NH2CH2CO2¯ binds to cobalt through…

A: This question is related to stereochemistry. Stereoisomers are the molecules having the same…

Q: [2] For the following pair of compounds, identify the most thermodynamically stable complex…

A: The compound containing chelate ring is more stable than non chelating compound. In the 2nd complex…

Q: CFSE and total spin moment

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Q: Heating 2.0 mol of a coordination compound gives 1.0mol NH3, 2.0 mol H2O, 1.0 mol HCl, and 1.0…

A: The chemical equation must be:

Q: How does the ligand relate to the complex in the pictureș i want explan and draw FeCl3 + 3 CH3COONH4…

A: Ligands are ions or neutral molecules that bond to a central metal atom or ion.

Q: Sketch structure of Mo(DMe) Cl2 (NMe,)2 , thhen apply ean to this complex showing ligand analysis…

A: The given chemical formula is: Mo(DMe) Cl2 (NMe)2 Assuming that DMe is OMe (methoxy group). The new…

Q: What is the full name of DMG? What is role of DMG in complex formation? 2. What is the structure of…

A: 1) DMG is referred to as Dimethyl glyoxime and the role of DMG in complex formation is in the…

Q: Consider the below ligand. If any atom with a lone pair of electrons can coordinate with a metal,…

A: A atom contain a lone pair of electrons can coordinate with metal. Then the number of donor atoms in…

Q: Each of a series of ligands, A, B and C can bind Li' ions. The values of AH (KJmol') for the…

A: The stability of coordination complex is an important factor that decides the stability and…

Q: Foreach of the following pairs of complexes, identify the one that has the larger Crstal Field…

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Q: In the complex Hs(CN)54 how many transition allowed could this complex have 2 4 None of them

A: Calculation of oxidation state in Hs(CN)54-: x+(-1×5)=-4x=+1 The electronic configuration of Hs+ is…

Q: Which coordination complex has the greatest A,? O [ScI,j³- O [Sc(NH,),J³+ O [Sc(H,O),J³* O…

A: Given  Complex = [ ScI6 ]3- , [ Sc ( NH3 )6 ]3+  , [ Sc( H2O)6 ]3+ , [ Sc ( en )3 ]3+ ∆0  = ?

Q: Based on the complex below, what would be the number of Co-Cl vibrational bands that would appear on…

A: According to question, Given complex, trans-CoNH35Cl2+

Q: The complex trans-[Co(en)2Cl2]+ undergoes substitution of Cl- by H2O slower than the complex…

A: To explain: The complex trans-[Co(en)2Cl2]+ undergoes substitution of Cl- by H2O slower than the…

Q: Which of the following statements about 10Dq is false? A. In the [CoX(NH3)5]n+ complex, the color…

A: The energy difference in the coordination compound related to colour.In  Strong field ligand,higher…

Q: calculat dlta E for each complex Trans complex : G= 355 microsiemens A= 450 nm Cis complex : G=250…

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Q: Z= Determine the coordination compound formula: 1.500=3 Coordination compound Formula: (0INH3)5 Cl 2…

A: Coordination compounds are the compounds which are the complex in which the metal atom is surrounded…

Q: Part A How many unpaired electrons are in the d orbitals of an octahedral complex of Ru3+  assuming…

A: In strong field, electrons enter the eg orbitals only when t2g orbitals are completely filled.

Q: [Mn(H2O)6]?* complex has an extremely pale color, attributable to transitions which are formally…

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Q: Which of the following lignads is ( are ) considered as chelate ligand * асас O phen O en O trien O…

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Q: What is the name of the complex [Al(H2O)2Br4]? O none of these O bisaquaterbromoaluminate(lI) ion O…

A: Option B is correct

Q: Describe the conditions that favor the formation of complexes with a low number of coordinates

A: Coordination complex is formed when ligand donate electron pair to central metal atom.

Q: What is the CFSE of this complex? State the oxidation state and hybridisation of the metal center

A: Solved in step 2.

Q: The three complex ions [Mn(CN),]³-, [Mn(CN),J*¯, and [Mn(CN),]³- have all been synthesized and all…

A: All three complexes has cyanide ligand, CN- which is a strong field ligand , thus all complexes are…

Q: Using the ligands ethylenediamine (H2NCH2 CH2NH2) and bromide anions, design a cationic chiral…

A: Chiral complex is defined as the atom which has all the substituents different or it doesn't has any…

Q: he color? Explain   appears light

A: A complex compound show color because the central atom present in the complex compound absorb some…

Q: Consider the below complex. Which of the labeled complexes is its enantiomer? A В D

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